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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 23, Number 9
BKCSDE 23(9)
September 20, 2002 

Mass-analyzed Threshold Ionization Spectrometry with Scrambling Field Optimized for the Study of State-selective Ion Reaction Dynamics
Sang Tae Park, Hong Lae Kim, Myung Soo Kim
Mass-analyzed threshold ionization
Mass-analyzed threshold ionization (MATI) technique is optimized to generate substantial amount of state-selected molecular ions sufficient for dynamics study. The main strategy is to stabilize intermediate (n = 100- 200) Rydberg states by l,m-mixing induced by AC field. Electrical jitter inherent in high voltage switching is utilized for this purpose. A related technique to locate the MATI onset is also described.
1247 - 1252
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