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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 23, Number 2
BKCSDE 23(2)
February 20, 2002

Title	Two Photon Dissociation of Benzene, Phenylacetylene, and Benzaldehyde at 243 nm: Translational Energy Releases in the H Atom Channel
Author	Seung Keun Shin, Hong Lae Kim, Chan Ryang Park
Keywords	Dissociation, Benzene, Translational energy.
Abstract	Hydrogen atom production channels from photodissociation of benzene, phenylacetylene, and benzaldehyde at 243 nm have been investigated by detecting H atoms using two photon absorption at 243.2 nm and induced fluorescence at 121.6 nm. Translational energies of the H atoms were measured by Doppler broadened H atom spectra. By absorption of two photons at 243 nm, the H atoms are statistically produced from benzene and phenylacetylene whereas the H atoms from the aldehyde group in benzaldehyde are produced from different pathways. The possible dissociation mechanisms are discussed from the measured translational energy releases.
Page	286 - 290
Full Text	PDF

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