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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 21, Number 9
BKCSDE 21(9)
September 20, 2000 

The "Trivial” Mechanism for the Photo-Fries Reaction of Phenyl Acetate and Biphenylyl Acetates
Hyo Jung Yoon, Seung Hye Ko, Mee Kyung Ko, Woo Ki Chae*
The mechanism for the photo-Fries rearrangement of phenyl acetate andbiphenylyl acetates were reinvestigat-ed in phenol (or phenol derivatives) containing media. The results showed that the phenol (or phenol deriva-tives) which is the most common by-product of Fries reaction reacts with acyl radical togive Fries-product. These phenol (or phenol derivatives) contributions to the Fries-products were suggested as the Trivial mecha-nism for the photo-Fries reaction.
901 - 904
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