KCS Publications

HOME > Search > Browsing(JKCS) > Archives

Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 43, Number 2
JKCSEZ 43(2)
April 20, 1999

Title	Kinetics and Dynamics on Inhibition Effect of Chlorinated Hydrocarbon in Combustion Reaction : The Ingibition Effect of CH3Cl on the Ignition of C2H6 염소계 탄화수소의 연소 억제 효과에 관한 반응속도 및 동력학 연구 : C2H6 점화 과정에서 CH3Cl 억제 효과
Author	Kuan Soo Shin, Wee Kyung Kang, Seung Bo Shim, Sung Bae Jee 신권수, 강위경, 심승보
Keywords
Abstract	소량의 CH3Cl 기체를 첨가한 C2H6-O2-Ar 혼합 기체의 점화 지연 시간을 반사 충격파 이후의 온도가 1270∼1544 K인 범위에서 측정하였다. 실험 결과 CH3Cl기체가 C2H6 기체의 점화 과정을 지연시킴을 알 수 있었고, CH3Cl 기체의 농도가 증가함에 따라 점화 지연 시간이 증가함을 알 수 있었다. 그리고 C2H6-CH3Cl-O2-Ar 혼합 기체에서 CH3Cl 기체의 점화 억제 효과를 반응 메카니즘 시각으로 살펴보기 위하여 컴퓨터를 이요한 모의 실험을 수행하였다. The ignition delay times behind reflected shock waves in C2H6-O2-Ar systems containing CH3CI were measured for the range of temperatures between 1270 and 1544 K. The measurements indicated that CH3CI inhibited the ignition of ethane ignition and the inhibition effects increased with increasing CH3Cl concentration. To clarify the inhibition effects of CH3CI from the viewpoint of the reaction mechanism, computational analyses were performed in C2H6-CH3CI-O2-Ar mixtures.
Page	150 - 155
Full Text	PDF

How to access to the WOL for The Bulletin of the Korean Chemical Society ?

The Bulletin of the Korean Chemical Society will be co-published with Wiley-VCH from 2015 towards. The online version of the Journal will thus be available on Wiley Online Library, Wiley(-VCH)'s global online platform.

KCS members can get a free online access to the Bulletin of the Korean Chemical Society in WOL.

Free Access to WOL