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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 39, Number 10
JKCSEZ 39(10)
August 20, 1995 

 
Title
Preparation of Silane Dendrimer (Ⅱ)

나무가지꼴 실란 거대분자의 제법 (Ⅱ)
Author
Chungkyun Kim*, Eunmi Park, Eunju Kang

김정균*, 박은미, 강은주
Keywords
Abstract
96개의 allyl기를 가진 나무가지꼴 실란 거대분자를 alkenylation과 hydrosilylation의 반복된 과정을 경유하여 매우 높은 수율로 합성하였다. 이 두 과정을 통해서 만들어진 나무가지꼴 거대분자는 크로마토그래피법을 이용한 정제법(silica gel, chloroform)에서 순수한 물질을 얻어졌음이 1H, 13C NMR과 원소분석등에 의해 확인되었다.

Silane dendrimer with 96 allylic end groups has been synthesized in excellent yield using repetitive alkenylation-hydrosilylation cycles. Each of the two steps provided the products in almost quantitative yields. After a simple chromotograpic purification (silica gel, chloroform), pure dendrimers were obtained and their purity was checked with 1H, 13C NMR spectroscopic method and elemental analysis.

Page
799 - 805
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