ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 29, Number 3
JKCSEZ 29(3)
June 20, 1985 

Dioxomolybdenum(Ⅵ) complexes, MoO2(H-Sal-R)2, R; arylamines, have been synthesized by reactions of dioxobis (salicylaldehydato) molybdenum(Ⅵ) with various primary amines. These complexes have been characterized by electric conductivity and spectroscopic studies. Infrared, uv-vis, and proton nmr spectra show that the complexes are six-coordinated with cis-MoO2 group. And mass spectra indicates that the combining ratios for Mo (Ⅵ)-ligand are 1 : 2. They are yellow, stable for a considerably long time in the atmosphere at room temperature and slightly soluble in alcohol, dichloromethane and dimethylformamide but insoluble in benzene, ether and carbon tetrachloride.