Current time in Korea 02:30 May 28 (Sun) Year 2017 KCS KCS Publications
KCS Publications
My Journal Log In Register
HOME > Search > Browsing(BKCS) > Archives

Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 30, Number 3
BKCSDE 30(3)
March 20, 2009 

 

535  

Synthesis of D-erythro-Sphingosine from D-ribo-Phytosphingosine
Hyun Joon Ha*, Doo Ha Yoon, Lae Sung Kang, Myeng Chan Hong, Won Koo Lee*
Keywords: D-erythro-Sphingosine, D-ribo-Phytosphingosine, Dehydration, Oxazolidin-2-one
DOI: https://doi.org/10.5012/bkcs.2009.30.3.535

Abstract | Full Text: PDF


537  

Synthetic Studies on Tedanolide: Stereoselective Synthesis of the C13-C21 Fragment
Su Ho Park, Jae Ki Min, Se Hwan Park, Hyo Won Lee*
Keywords: Macrolide, Tedanolide, Antitumor compounds, Metal-mediated allylation
DOI: https://doi.org/10.5012/bkcs.2009.30.3.537

Abstract | Full Text: PDF


539  

A Wide-range Luminescent pH Sensor Based on Ruthenium(II) Complex
Hyung Jin Kim*, Yong Chae Jeong, Joon Heo, Jong Il Rhee, Kwang Jin Hwang
Keywords: Optical pH sensor, Luminescent indicator, Ruthenium complex
DOI: https://doi.org/10.5012/bkcs.2009.30.3.539

Abstract | Full Text: PDF


541  

A Green Protocol for Asymmetric Epoxidation of Olefins Catalyzed by Carbon Dioxide Soluble Chiral Salen-Mn(III) Complexes in Supercritical CO2
Chunji Gao, Wooseob Shin, Jungmin Han, Donggyun Han, M Adharvana Chari, Hongdoo Kim, Kwang Hyun Ahn*
Keywords: Asymmetric epoxidation, Olefins, CO2 soluble manganese salen, Enantioselectivity, Supercritical carbon dioxide
DOI: https://doi.org/10.5012/bkcs.2009.30.3.541

Abstract | Full Text: PDF


543  

Single-crystal Structure of Fully Dehydrated and Largely NH4+-exchanged Zeolite Y (FAU, Si/Al = 1.70), |(NH4)60Na11|[Si121Al71O384]-FAU
Sung Man Seo, Ghyung Hwa Kim*, Young Hun Kim, Lianzhou Wang, Gao Qing Lu, Woo Taik Lim*
Keywords: Zeolite Y, Ammonium-exchange, Single-crystal X-ray diffraction, Crystal structure
DOI: https://doi.org/10.5012/bkcs.2009.30.3.543

Abstract | Supporting Information | Full Text: PDF


551  

Applications of Cross-linked Poly(4-vinylpyridine/styrene) Copolymer-supported Ytterbium(III) Triflate in Mannich-type Reaction: Three Component One-pot Synthesis of β-Aminoketones
Sang Hyeup Lee*, Byoung Se Lee*
Keywords: Polymer-supported catalyst, Poly(4-vinylpyridine/styrene), Ytterbium(III) triflate, Mannich-type reaction
DOI: https://doi.org/10.5012/bkcs.2009.30.3.551

Abstract | Full Text: PDF


556  

Study on Thermodynamics of Three Kinds of Benzindocarbocyanine Dyes in Aqueous Methanol Solution
Wei Huang, Lan Ying Wang*, Yi Le Fu, Ji Quan Liu, You Ni Tao, Fang Li Fan, Gao Hong Zhai, Zhen Yi Wen
Keywords: Benzindocarbocyanine dye, Thermodynamic property, Aggregation state
DOI: https://doi.org/10.5012/bkcs.2009.30.3.556

Abstract | Full Text: PDF


561  

Synthesis of Some Imidazopyrazolopyrimidines, Pyrazolopyrimidopyrimidines and Pyrazolopyrimidothiazines
A M Elkhawaga, A M Kamal El Dean*, Sh M Radwan, M M Ahmed
Keywords: Synthesis, Pyrazolopyrimidines, Imidazopyrazolopyrimidines, Pyrimidopyrazolopyrimidines, Pyrimidopyrazolothiazines
DOI: https://doi.org/10.5012/bkcs.2009.30.3.561

Abstract | Full Text: PDF


567  

Effects of the Counter Ion Valency on the Colloidal Interaction between Two Cylindrical Particles
Inho Lee, Hyunbae Dong, Juyoung Choi, Sang Yup Lee*
Keywords: Electrical repulsion, Derjaguin approximation, Ion valency, Cylinder
DOI: https://doi.org/10.5012/bkcs.2009.30.3.567

Abstract | Full Text: PDF


573  

First Hydrogelation of Discrete Metal Complexes. Structures and Fluxional Behavior of Cyclopalladium(II) Complexes
Young Mee Na, Tae Hwan Noh, Byung Jo Ha, Jongki Hong, Ok Sang Jung*
Keywords: Catenane, Hydrogelation, Metallacycles, Palladium, Si ligands
DOI: https://doi.org/10.5012/bkcs.2009.30.3.573

Abstract | Supporting Information | Full Text: PDF


577  

A Cell-based Method to Monitor the Interaction between Hepatitis B Virus Capsid and Surface Proteins
Yun Kyoung Kim, Soo Jin Oh, Bong Suk Jin, Chanhoo Park, Hyesung Jeon, Doo Wan Boo, Yeon Gyu Yu*
Keywords: HBV, PreS, Capsid, Interaction
DOI: https://doi.org/10.5012/bkcs.2009.30.3.577

Abstract | Full Text: PDF


582  

Electrochemistry of Hemoglobin in the Chitosan and TiO2 Nanoparticles Composite Film Modified Carbon Ionic Liquid Electrode and Its Electrocatalysis
Wei Sun*, Xiaoqing Li, Shufeng Liu, Kui Jiao
Keywords: Hemoglobin, TiO2 nanoparticles, Ionic liquid, Carbon paste electrode, Electrochemistry
DOI: https://doi.org/10.5012/bkcs.2009.30.3.582

Abstract | Full Text: PDF


589  

DFT Study of p-tert-Butylcalix[6]aryl Ester Complexed with Alkylammonium Ions
Kwangho Kim, Jong In Choe*
Keywords: DFT, B3LYP/6-31G(d,p), Calix[6]aryl ester, Alkylammonium ions, Hydrogen bond
DOI: https://doi.org/10.5012/bkcs.2009.30.3.589

Abstract | Full Text: PDF


595  

He-Polymer Microchip Plasma (PMP) System Incorporating a Gas-Liquid Separator for the Determination of Chlorine Levels in a Sanitizer Liquid
Joosuck Oh, Y H Kim, H B Lim*
Keywords: He plasma, Atomic emission, Determination of chlorine, Polymer microchip plasma
DOI: https://doi.org/10.5012/bkcs.2009.30.3.595

Abstract | Full Text: PDF


599  

Conjugates of Enkephalin Analogs: Synthesis and Discrimination of μ and δ Opioid Receptors Based on Membrane Compartment Concept
Nam Joo Hong*, Dong Hoon Jin, Eun Young Hong
Keywords: Enkephalin, Conjugate, Membrane compartment, Bioactivity
DOI: https://doi.org/10.5012/bkcs.2009.30.3.599

Abstract | Full Text: PDF


608  

Solid-state MAS NMR Investigation on the Local Structures
of xV2O5-B2O3-yNa2O Glasses
Sun Ha Kim, Oc Hee Han*, Jae Pil Kang, Seung Ki Song
Keywords: Glass structure, Nuclear magnetic resonance, MAS NMR
DOI: https://doi.org/10.5012/bkcs.2009.30.3.608

Abstract | Full Text: PDF


613  

3D-QSARs of Herbicidal 2-N-Phenylisoindolin-1-one Analogues as a New Class of Potent Inhibitors of Protox
Min Gyu Soung, Yoon Jung Lee, Nack Do Sung*
Keywords: 3D-QSAR, CoMFA, CoMSIA, 2-N-Phenylisoindolin-1-one analogues, Protox
DOI: https://doi.org/10.5012/bkcs.2009.30.3.613

Abstract | Full Text: PDF


618  

Synthesis and Physical Properties of Decylbithiophene End-Capped Oligomers Based on Naphthalene, Anthracene and Benzo[1,2-b:4,5-b’]dithiophene
Sang Hun Jang, Truong Ba Tai, Min Kyu Kim, Jeong Woo Han, Yun Hi Kim, Sung Chul Shin, Yong Jin Yoon, Soon Ki Kwon*, Sang Gyeong Lee*
Keywords: Suzuki coupling, Photoluminescence, Cyclic voltametry, Thermal gravimetric analysis, Differential scanning calorimetry
DOI: https://doi.org/10.5012/bkcs.2009.30.3.618

Abstract | Full Text: PDF


623  

Structural Properties of Fibril-forming Segments of α-Synuclein
Jeseong Yoon, Joonho Park, Soonmin Jang, Kyunghee Lee, Seokmin Shin*
Keywords: Replica-exchange molecular dynamics, Fibril formation, α-Synuclein, Natively unstructured protein, Representative structure
DOI: https://doi.org/10.5012/bkcs.2009.30.3.623

Abstract | Full Text: PDF


630  

Synthesis of Bi2WO6 Nanometer Sheet Shaped and Approach to the Photocatalysis
Dong Young Kim, Sujung Kim, Misook Kang*
Keywords: Bi2WO6, Thermal treatment, Photoluminescence, Methyl orange removal
DOI: https://doi.org/10.5012/bkcs.2009.30.3.630

Abstract | Full Text: PDF


636  

Novel and Efficient Palladium Complexes with β-Ketoiminate Ligands for the Polymerization of Norbornene
Dong Hwan Lee, Yoon Joo Hwang, Jin San Yoon, Moon Kun Choi, Ik Mo Lee*
Keywords: Palladium complexes, β-Ketoiminate ligands, Norbornene polymerization, Activators, Structures
DOI: https://doi.org/10.5012/bkcs.2009.30.3.636

Abstract | Full Text: PDF


647  

Blue OLEDs Utilizing Spiro[fluorene-7,9'-benzofluorene]-type Compounds as Hosts and Dopants
Joo Han Kim, Young Min Jeon, Ji Geun Jang, Sangouk Ryu, Ho Jung Chang, Chil Won Lee, Joon Woo Kim, Myoung Seon Gong*
Keywords: Blue OLED, Host, Dopant, Spiro[fluorene-7,9′-benzofluorene], Color purity
DOI: https://doi.org/10.5012/bkcs.2009.30.3.647

Abstract | Full Text: PDF


653  

Fabrication of 3-Dimensional LiMn2O4 Thin Film
Bo Gun Park, Jea Hyeok Ryu, Won Youl Choi, Yong Joon Park*
Keywords: 3-D microbattery, Sol-gel, Template, LiMn2O4, Thin film
DOI: https://doi.org/10.5012/bkcs.2009.30.3.653

Abstract | Full Text: PDF


657  

The Effect of Surface Modification with La-M-O (M = Ni, Li) on
Electrochemical Performances of Li[Ni0.8Co0.15Al0.05]O2 Cathode
Jea Hyeok Ryu, Seuk Buom Kim, Yong Joon Park*
Keywords: Surface modification, Electrochemical property, Thermal stability, Cathode, Lithium battery
DOI: https://doi.org/10.5012/bkcs.2009.30.3.657

Abstract | Full Text: PDF


661  

Synthesis and Properties of Novel Y-type Nonlinear Optical Polyester Containing Cyanovinylthiophene with Enhanced Thermal Stability of Second Harmonic Generation
Ga Young Lee, Jin Hyang Kim, Han Na Jang, Dong Seon Won, Hyo Jin No, Ju Yeon Lee*, Bum Ku Rhee, Hee Dok Choi
Keywords: NLO, Polyester, Differential scanning calorimetry (DSC), Atomic force microscopy (AFM), Second harmonic generation (SHG)
DOI: https://doi.org/10.5012/bkcs.2009.30.3.661

Abstract | Full Text: PDF


667  

Experimental Evidence of the Mobility of Hydroperoxyl/Superoxide Anion Radicals from the Illuminated TiO2 Interface into the Aqueous Phase
Bum Gun Kwon, Jeyong Yoon*
Keywords: TiO2 photocatalyst, Hydroperoxyl/superoxide anion radical, Knotted tubing reactor, Chemiluminescence, MCLA
DOI: https://doi.org/10.5012/bkcs.2009.30.3.667

Abstract | Full Text: PDF


671  

Effect of Graphite Nanofibers on Poly(methyl methacrylate) Nanocomposites for Bipolar Plates
Min Kang Seo, Soo Jin Park*
Keywords: Graphite nanofibers, Polymer, Composite materials, Thermal properties, Mechanical properties
DOI: https://doi.org/10.5012/bkcs.2009.30.3.671

Abstract | Full Text: PDF


675  

High Photocatalytic Activity of Gd2O2S:Tb Modified Titanium Dioxide Films
Bum Goo Kim*, Hak Guen Lee, Hee Sung Kim, Young Soon Kim
Keywords: Titanium dioxide, Gd2O2S:Tb, Photocatalysts, PL
DOI: https://doi.org/10.5012/bkcs.2009.30.3.675

Abstract | Full Text: PDF


679  

Synthesis and Reactivity of a Mononuclear Manganese(II) Complex Having Pseudo-Seven Coordination Environment
Jeehee Yoon, Mi Sook Seo, Youngmee Kim, Sung Jin Kim, Sungho Yoon*, Ho G Jang*, Wonwoo Nam*
Keywords: Bioinorganic chemistry, Seven coordination, High-valent manganese-oxo, Oxygenation, N-Dealkylation
DOI: https://doi.org/10.5012/bkcs.2009.30.3.679

Abstract | Full Text: PDF


683  

Slurry Phase Reaction of Elemental Silicon with Methanol in the Presence of Copper: Direct Synthesis of Trimethoxysilane
Joon Soo Han, Joo Hyun Cho, Myong Euy Lee, Bok Ryul Yoo*
Keywords: Copper, Silicon, Methanol, Trimethoxysilane, Alkoxysilane
DOI: https://doi.org/10.5012/bkcs.2009.30.3.683

Abstract | Full Text: PDF


687  

Synthesis and Antibacterial Activity of 1,3-Diallyltrisulfane Derivatives
Fang Kui Ren, Xiao Yan He, Li Deng, Bo Heng Li, Dong Soo Shin*, Zhu Bo Li*
Keywords: Diallylsulfane, Diallyldisulfane, Diallyltrisulfane, Antimicrobial activity, Biological activity
DOI: https://doi.org/10.5012/bkcs.2009.30.3.687

Abstract | Full Text: PDF


691  

A Convenient Synthesis of Polycyclic γ-Lactams via Pauson-Khand Reaction
Seok Won Kang, Yong Hoon Kim, Hea Jeong Kim, Joo Hee Lee, Sung Hoon Kim*
Keywords: Polycyclic γ-lactams, Pauson-Khand reaction, 5,6,5 Fused ring systems, Co2(CO)8
DOI: https://doi.org/10.5012/bkcs.2009.30.3.691

Abstract | Full Text: PDF


695  

Stereoselective Transformation of Phytosphingosine to Safingol
Nari Kim, Sun Hee Lee, Sung Keon Namgoong*
Keywords: Safingol, Phytosphingosine, Phase transfer catalysis, Epoxide-forming reaction, Reduction
DOI: https://doi.org/10.5012/bkcs.2009.30.3.695

Abstract | Full Text: PDF


700  

H+ Ion Migration in Water Filled Carbon Nanotube
Song Hi Lee
Keywords: Molecular dynamics simulation, OSS2 potential, Proton transfer, Carbon nanotube
DOI: https://doi.org/10.5012/bkcs.2009.30.3.700

Abstract | Full Text: PDF


703  

A New Acylated Stilbene Glycoside from Acanthopanax brachypus
Hao bin Hu, Jun Fan*
Keywords: Acanthopanax brachypus, Araliaceae, Acylated stilbene glycoside, Phenolic glycoside
DOI: https://doi.org/10.5012/bkcs.2009.30.3.703

Abstract | Full Text: PDF


707  

Angiopoietin-like 3 (ANGPTL3) Stimulates Human Umbilical Vein Endothelial Cell Tube Formation and Vascular Endothelial Growth Factor Production
Mina Song, Sayeon Cho*
Keywords: Angiopoietin-like 3 (ANGPTL3), Angiogenesis, Vascular endothelial growth factor (VEGF)
DOI: https://doi.org/10.5012/bkcs.2009.30.3.707

Abstract | Full Text: PDF


710  

An Efficient Synthesis of 2-Phenyl-4H-1-benzothiopyran-4-ones from Thiosalicylic Acid
Jae In Lee
Keywords: 2-Phenyl-4H-1-benzothiopyran-4-ones, Thioflavones, Condensation, Cyclization
DOI: https://doi.org/10.5012/bkcs.2009.30.3.710

Abstract | Full Text: PDF


713  

Preparation of a Superhydrophobic Film on Micro Lens Arrays Pattern
Young Wook Choi*, Sairan Eom, JungEun Han, Yong Shin Kim, Jisun Lee, Daewon Sohn*
Keywords: Superhydrophobic, Contact angle, Self-cleaning, Lotus effect, Biomimic surface
DOI: https://doi.org/10.5012/bkcs.2009.30.3.713

Abstract | Full Text: PDF


716  

Two New Lignans from the Roots of Saururus chinensis
Chang Seob Seo, Ming Shan Zheng, Li Ying, Yurngdong Jahng, Hyeun Wook Chang, Jong Keun Son*
Keywords: Saururus chinensis, Saururaceae, Lignan
DOI: https://doi.org/10.5012/bkcs.2009.30.3.716

Abstract | Full Text: PDF


719  

Rhodamine Derivative Bearing Histidine Binding Site as a Fluorescent Chemosensor for Hg2+
Soo Kyung Kwon, Ha Na Kim, Jeong Hwa Rho, K M K Swamy, S M Shanthakumar, Juyoung Yoon*
Keywords: Fluorescent chemosensor, Rhodamine, Mercury ion sensor
DOI: https://doi.org/10.5012/bkcs.2009.30.3.719

Abstract | Full Text: PDF


722  

A New Stationary Phase Prepared by Polymerization of Styrene on Initiator Bonded Porous Silica
Sung Soon Kim, Won Jo Cheong*
Keywords: Initiator silica, RAFT polymerization, Polystyrene bound silica, Improved column efficiency
DOI: https://doi.org/10.5012/bkcs.2009.30.3.722

Abstract | Full Text: PDF


726  

Pd-Mediated Cross-Coupling Reactions between the Bromide of Baylis-Hillman Adduct and Organostannanes
Saravanan Gowrisankar, Sung Hwan Kim, Jae Nyoung Kim*
Keywords: Palladium, Cross-coupling, Baylis-Hillman adduct, Organostannanes
DOI: https://doi.org/10.5012/bkcs.2009.30.3.726

Abstract | Full Text: PDF


729  

Benzyl Cation Formation from the Reaction of Benzyl Alcohol with Thianthrene Cation Radical
Hyung Min Moon, Wang Keun Lee*
Keywords: Benzyl cation, Benzylacetamide, Thianthrene cation radical
DOI: https://doi.org/10.5012/bkcs.2009.30.3.729

Abstract | Full Text: PDF


731  

Synthesis and Nonlinear Optical Properties of Novel Polyester with 2,3-Dioxybenzylidenecyanoacetate
Han Na Jang, Hyo Jin No, Ju Yeon Lee*
Keywords: Nonlinear optics, Polyester, Thermal stability, Second harmonic generation, Relaxation of dipole alignment
DOI: https://doi.org/10.5012/bkcs.2009.30.3.731

Abstract | Full Text: PDF


735  

Elimination of Δ3→Δ2 Isomerization in the Synthesis of a Cephem-Containing Chemical Inducer of Dimerization through a Modified Purification
Sang Soo Hah*, Jungahn Kim
Keywords: Cephem, Δ3→Δ2 Isomerization, Chemical inducer of protein dimerization
DOI: https://doi.org/10.5012/bkcs.2009.30.3.735

Abstract | Full Text: PDF


739  

New Alkaloids from Oryza sativa cv. Heugjinjubyeo Bran
Eun Sil Kim, Jin Won Hyun, Jin Chul Shin, Ha Sook Chung*
Keywords: Oryza sativa cv. Heugjinjubyeo, Purple rice, Alkaloid, HR-MS, 2D-NMR
DOI: https://doi.org/10.5012/bkcs.2009.30.3.739

Abstract | Full Text: PDF


742  

Spirodienal, a New Spiroketal from Sorangium cellulosum
Jong Woong Ahn
Keywords: Myxobacteria, Spiroketal, Structure determination, Antifungal
DOI: https://doi.org/10.5012/bkcs.2009.30.3.742

Abstract | Full Text: PDF


745  

Efficient Synthesis of a Highly Active Catalyst for CO2/Epoxide Copolymerization
Jaeki Min, Jong Eon Seong, Sung Jae Na, Anish Cyriac, Bun Yeoul Lee*
Keywords: Carbon dioxide, Epoxide, Salen-cobalt complexes, Quaternary ammonium salt, Polymerization
DOI: https://doi.org/10.5012/bkcs.2009.30.3.745

Abstract | Full Text: PDF


749  

Kinetics and Mechanism of the Aminolysis of Aryl Thionocarbamates in Acetonitrile
Sun Young Park, Hyuck Keun Oh*
Keywords: Nucleophilic substitution, Aryl thionocarbamates, Cross-interaction constant, Kinetic isotope effects, Concerted mechanism
DOI: https://doi.org/10.5012/bkcs.2009.30.3.749

Abstract | Full Text: PDF