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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 29, Number 2
BKCSDE 29(2)
February 20, 2008 

 

297  

Studies on the Total Synthesis of Amphidinolide O (III): A Stereoselective Synthesis of C1-C11 Fragment
Jong Woo Kim, Sun-Ju Kong, Yeo-Jin Kim, Duck-Hyung Lee*
Keywords: Amphidinolide O, Cytotoxic macrolide, Stereoselective synthesis, Brown crotylation
DOI: https://doi.org/10.5012/bkcs.2008.29.2.297

Abstract | Full Text: PDF


299  

Conformationally Restricted Ratiometric Fluorescent Receptor for the Recognition of Adipate
Tae Young Joo, Narinder Singh, Hee Jung Jung, Doo Ok Jang*
Keywords: Ratiometry, Dicarboxylate, Fluorescence, Adipate
DOI: https://doi.org/10.5012/bkcs.2008.29.2.299

Abstract | Full Text: PDF


301  

Regioselective Cleavage of Phenyl- or Alkyl-Substituted Epoxides with Al-Fluorodiisobutylalane
Jin Soon Cha*, Seung Jin Park, Se Jin Yu, Seung Kook Kim, Oh Oun Kwon
Keywords: Epoxide, Regioselective cleavage, Reduction, Al-Fluorodiisobutylalane, MPV type reaction
DOI: https://doi.org/10.5012/bkcs.2008.29.2.301

Abstract | Full Text: PDF


303  

Preparation, Characterization and Toxicological Impacts of Monodisperse Quantum Dot Nanocolloids in Aqueous Solution
Chansik Park, Do Hyun Kim, Min Jung Kim, Tae Hyun Yoon*
Keywords: Engineered nanoparticles, Quantum dots, Cytotoxicity, Microorganisms
DOI: https://doi.org/10.5012/bkcs.2008.29.2.303

Abstract | Full Text: PDF


305  

Toward an Accurate Self-interaction Binding Energy of Magic Cluster TiAu4
Young-Kyu Han, Jong Chan Kim, Jaehoon Jung, Ungsik Yu*
Keywords: TiAu4, Binding energy, Dimeric interaction
DOI: https://doi.org/10.5012/bkcs.2008.29.2.305

Abstract | Full Text: PDF


309  

Effect of Silicon Content over Fe-Cu-Si/C Based Composite Anode for Lithium Ion Battery
Chil-Hoon Doh*, Hye-Min Shin, Dong-Hun Kim, Young-Dong Chung, Seong-In Moon, Bong-Soo Jin, Hyun-Soo Kim, Ki-Won Kim, Dae-Hee Oh, Angathevar Veluchamy
Keywords: High energy mechanical milling, Fe(1)Cu(1)Si(3.5), Fe(1)Cu(1)Si(2.5), Anode, Li-ion battery
DOI: https://doi.org/10.5012/bkcs.2008.29.2.309

Abstract | Full Text: PDF


313  

Asymmetric Ring Opening of Epoxides Catalyzed by Novel Heterobimetallic Schiff-Bases Containing Transition Metal Salts
Rahul B Kawthekar, Wen-tao Bi, Geon-Joong Kim*
Keywords: Kinetic resolution, Ring opening reactions, Heterobimetallic catalyst, Chiral intermediate
DOI: https://doi.org/10.5012/bkcs.2008.29.2.313

Abstract | Full Text: PDF


319  

Aromatic Formation from Vinyl Radical and Acetylene. A Mechanistic Study
Debby Natalia, Antonius Indartoa*,
Keywords: Vinyl radical, Acetylene, Aromatic, Ring closure, Chain elongation
DOI: https://doi.org/10.5012/bkcs.2008.29.2.319

Abstract | Full Text: PDF


323  

Discovery of Novel Transcription Factor Inhibitors Using a Pyrazole-based Small Molecule Library
Hyung-Ho Ha, B. Moon Kim*
Keywords: Transcription factor, 5-Amino-3-pyrazole carboxamide, HIF-1α, NF-AT, Inhibitor
DOI: https://doi.org/10.5012/bkcs.2008.29.2.323

Abstract | Full Text: PDF


328  

Effect of Catalyst Preparation on the Selective Hydrogenation of Biphenol over Pd/C Catalysts
Hong-Baek Cho, Jai-Hyun Park, Bum-Eui Hong, Yeung-Ho Park*
Keywords: Biphenol hydrogenation, Pd/C preparation, Precipitation and deposition, Catalyst particle size, Metal distribution
DOI: https://doi.org/10.5012/bkcs.2008.29.2.328

Abstract | Full Text: PDF


335  

Synthesis and Characterization of Novel Red-Light-Emitting Materials with Push-Pull Structure Based on Benzo[1,2,5]thiadiazole Containing Arylamine as an Electron Donor and Cyanide as an Electron Acceptor
Jin Uk Ju, Sung Ouk Jung, Qing Hua Zhao, Yun Hi Kim*, Jong Tae Je, Soon Ki Kwon*
Keywords: Benzo[1,2,5]thiadiazole, Push-pull, Inhibited intermolecular interaction, Amorphous
DOI: https://doi.org/10.5012/bkcs.2008.29.2.335

Abstract | Full Text: PDF


339  

Trimerization of Isobutene over Solid Acid Catalysts: Comparison between Cation-exchange Resin and Zeolite Catalysts
Ji Woong Yoon, Sung Hwa Jhung*, Jong-San Chang*
Keywords: Isobutene, Trimerization, Zeolite, Cation-exchange resin
DOI: https://doi.org/10.5012/bkcs.2008.29.2.339

Abstract | Full Text: PDF


342  

Antiapoptotic Effect of Aurintricarboxylic Acid; Extracellular Action versus Inhibition of Cytosolic Protein Tyrosine Phosphatases
Dong Yoon Lee, Mee-Kyung Kim, Mi-Jeong Kim, Bharat Raj Bhattarai, Bhooshan Kafle, Keun-Hyeung Lee, Jae-Seung Kang*, Hyeongjin Cho*
Keywords: Apoptosis, Aurintricarboxylic acid, PC12 cells, Protein tyrosine phosphatase, Inhibitor
DOI: https://doi.org/10.5012/bkcs.2008.29.2.342

Abstract | Full Text: PDF


347  

Solution Structure and Backbone Dynamics of the Biotinylation Domain of Helicobacter pylori Biotin-carboxyl Carrier Protein
Jinwon Jung, Chul-Jin Lee, Young Ho Jeon, Chaejoon Cheong, Weontae Lee*
Keywords: BCCP, Backbone dynamics, Solution structure, NMR spectroscopy
DOI: https://doi.org/10.5012/bkcs.2008.29.2.347

Abstract | Full Text: PDF


352  

Rapid Determination of Chlorostyrenes in Fish by Freezing-Lipid Filtration, Solid-Phase Extraction and Gas Chromatography-Mass Spectrometry
Min-Sun Kim, Kwang-Sik Park, Heesoo Pyo, Jongki Hong*
Keywords: Fish, Chlorostyrenes, Freezing-lipid filtration, SPE, GC-MS
DOI: https://doi.org/10.5012/bkcs.2008.29.2.352

Abstract | Full Text: PDF


357  

Preparation of Boronated Heterocyclic Compounds Using Intramolecular Cyclization Reaction
Chai-Ho Lee*, Guo Fan Jin, Hyo-Suk Kim, Hiroyuki Nakamura, Yongseog Chung*, Jong-Dae Lee*
Keywords: Brain cancer therapy, Boronated heterocyclic compounds, Cytotoxicity
DOI: https://doi.org/10.5012/bkcs.2008.29.2.357

Abstract | Full Text: PDF


363  

Molecular Dynamics Free Energy Simulation Study to Rationalize the Relative Activities of PPARδ Agonists
Woojin Lee, Hwangseo Park*, Sangyoub Lee*
Keywords: Thermodynamic integration, Binding free energy, Molecular dynamics, PPARδ, Lead optimization
DOI: https://doi.org/10.5012/bkcs.2008.29.2.363

Abstract | Full Text: PDF


372  

Gallium(III) Ion Hydrolysis under Physiological Conditions
Brahim Hacht
Keywords: Gallium(III), Hydrolysis, Stability constants, Potentiometry, Physiological conditions
DOI: https://doi.org/10.5012/bkcs.2008.29.2.372

Abstract | Full Text: PDF


377  

Ring Flipping of Seven-membered and Eight-membered Dithienodisila-heterocycles
In-Sook Lee, Young-Woo Kwak*, Manik Kumer Ghosh, Joji Ohshita, Cheol Ho Choi*
Keywords: Dithienodisilacyclooctatriene, Oxadithienodisilacycloheptadiene, Ring flipping barrier, Twistingangle
DOI: https://doi.org/10.5012/bkcs.2008.29.2.377

Abstract | Full Text: PDF


381  

Identification and Functional Analysis of SEDL-binding and Homologue Proteins by Immobilized GST Fusion and Motif Based Methods
Ji-Man Hong, Mi Suk Jeong, Jae Ho Kim, Boo Gil Kim, Stephen R. Holbrook, Se Bok Jang*
Keywords: SEDL-binding proteins, Immobilized GST fusion, Motif analysis
DOI: https://doi.org/10.5012/bkcs.2008.29.2.381

Abstract | Full Text: PDF


389  

Synthesis of High Purity Carbon Nano Fibers and Hydrogen from Propane Decomposition
S. Tajammul Hussain*, Sheraz Gul, M. Mazhar, Faical Larachi
Keywords: Propane decomposition, Supported catalyst, Nanocarbons, COx free hydrogen
DOI: https://doi.org/10.5012/bkcs.2008.29.2.389

Abstract | Full Text: PDF


393  

Determination of Trace Elements of Ge and P in a Gold Bonding Wire by Inductively Coupled Plasma Atomic Emission Spectrometry
Sung-Min Choi, Gae-Ho Lee*, Jae-Kil Han
Keywords: ICP-AES, Gold, Trace, Ge, P
DOI: https://doi.org/10.5012/bkcs.2008.29.2.393

Abstract | Full Text: PDF


398  

A New Selective Membrane Electrode for Oxalate Based on N,N'-Bis(salicylidene)-2,2-dimethylpropane-1,3-diamine Ni(II)
M. Mazloum Ardakani*, F. Iranpoor, M. A. Karimi, M. Salavati-Niasari
Keywords: Ion-selective electrode, Oxalate, Potentiometry, Membrane
DOI: https://doi.org/10.5012/bkcs.2008.29.2.398

Abstract | Full Text: PDF


405  

Carbon-13 CP MAS NMR Study on Structures of Octadecyl Chains Influenced by Co-Presence of 3-Aminopropyl Chains on SBA-15
Oc Hee Han*, Yoon Kyung Bae, Soon Yong Jeong
Keywords: Solid-state NMR spectroscopy, SBA-15, 3-Aminopropyltrimethoxysilane, Octadecyltrimethoxysilane, Functionalized mesoporous materials
DOI: https://doi.org/10.5012/bkcs.2008.29.2.405

Abstract | Full Text: PDF


408  

Structural Basis of Functional Conversion of a Floral Repressor to an Activator: A Molecular Dynamics Simulation Study
Sukki Kang, Juyong Lee, Myeong Sup Lee, Chaok Seok*
Keywords: FLOWERING LOCUS T, TERMINAL FLOWER 1, Floral regulators, Molecular dynamics simulation, Hydrogen bond
DOI: https://doi.org/10.5012/bkcs.2008.29.2.408

Abstract | Full Text: PDF


413  

Synthesis of Mesoporous Carbons with Controllable N-Content and Their Supercapacitor Properties
Jeongnam Kim, Minkee Choi, Ryong Ryoo*
Keywords: Nitrogen doping, Mesoporous carbon, EDLC
DOI: https://doi.org/10.5012/bkcs.2008.29.2.413

Abstract | Full Text: PDF


417  

Synthesis and Binding Properties of 1,3,5-Tris(2-arylthiomethyl)mesitylene: A Selective Ag (I) Ionophore
Hong-Seok Kim*, Seon-Yun Bae, Ki Soo Kim, Jun-Hyeak Choi, Heung Jin Choi, Jun Ho Shim, Geun Sig Cha, Hakhyun Nam*
Keywords: Tripodal receptor, Mesitylene, NMR titration, ISE, Silver ion selective
DOI: https://doi.org/10.5012/bkcs.2008.29.2.417

Abstract | Full Text: PDF


422  

Reduced Burst Release from ePTFE Grafts: A New Coating Method for Controlled Drug Release
Hye Yeong Nam, Dae Joong Kim, Hyun Jung Lim, Byung Ha Lee, Insu Baek, Sang Hun Park, Jong-sang Park*
Keywords: ePTFE, Graft, Hemodialysis, Paclitaxel, Dipping
DOI: https://doi.org/10.5012/bkcs.2008.29.2.422

Abstract | Full Text: PDF


427  

The Strategy to Fabricate the MTiO3 (M = Sr, Ba) Thin Films by Laser Ablation
T. M. Im, J. Y. Park, H. J. Kim, H. K. Choi, K. W. Jung*, D. Jung*
Keywords: Thin film, Laser ablation, Ferroelectrics, Crystallization
DOI: https://doi.org/10.5012/bkcs.2008.29.2.427

Abstract | Full Text: PDF


431  

Selectivity of between K+ and Na+ Ions to 12-Crown-4: QSPR Analysis by a Monte Carlo Simulation Study
Hag-Sung Kim
Keywords: Stability constant, Quantitative solvent-polarity relationships (QSPR), Monte Carlo simulation
DOI: https://doi.org/10.5012/bkcs.2008.29.2.431

Abstract | Full Text: PDF


438  

Investigation of the Scanning Tunneling Microscopy Image, the Stacking Pattern and the Bias-voltage Dependent Structural Instability of 2,2'-Bipyridine Molecules Adsorbed on Au(111) in Terms of Electronic Structure Calculations
Youngsun Suh, Sung Soo Park, Jinhee Kang, Yong Gyoo Hwang, D. Jung, Dong Hee Kim, Kee Hag Lee*, M.-H. Whangbo
Keywords: 2,2'-Bipyridine on Au(111), Adsorbate-surface interaction, Scanning tunneling microscopy image interpretation, First principles calculations, Tight-binding band calculations.
DOI: https://doi.org/10.5012/bkcs.2008.29.2.438

Abstract | Full Text: PDF


445  

Surface-Enhanced Raman Scattering of Benzenethiol Adsorbed on Silver-Exchanged Copper Powders
Kuan Soo Shin*, Hyunwoo Ryoo, Yoon Mi Lee, Kwan Kim*
Keywords: Surface-enhanced Raman scattering, Copper powder, Silver dendrite, Galvanic exchange, Benzenethiol
DOI: https://doi.org/10.5012/bkcs.2008.29.2.445

Abstract | Full Text: PDF


450  

Physical Chemistry Research Articles Published in the Bulletin of the Korean Chemical Society: 2003-2007
Hosung Sun*, Sun Yeoul Lee, Choon Shil Lee
Keywords: Physical chemistry, Bulletin of the Korean Chemical Society, Journal of the American Chemical Society, The Journal of Physical Chemistry
DOI: https://doi.org/10.5012/bkcs.2008.29.2.450

Abstract | Full Text: PDF


463  

Method to Increase the Surface Area of Titania Films and Its Effects on the Performance of Dye-Sensitized Solar Cells
Young-Seon Ko, Min-Hye Kim, Young-Uk Kwon*
Keywords: Dye-sensitized solar cell, Titania-coating, Surface modification
DOI: https://doi.org/10.5012/bkcs.2008.29.2.463

Abstract | Full Text: PDF


467  

Reaction Temperature Dependent Formations of the Zero- and One-Dimensional ZnS:Mn Nanocrystals
Young-Ah Kim, Cheong-Soo Hwang*
Keywords: ZnS:Mn nanocrystal, Nano rod and dot mixture, Temperature dependent shape formation
DOI: https://doi.org/10.5012/bkcs.2008.29.2.467

Abstract | Full Text: PDF


471  

Synthesis, Cytotoxicity and Topoisomerase II Inhibition Study of New Thioxanthone Analogues
Sangwook Woo, Da-hye Kang, Jungsook Kim, Chong-Soon Lee, Eung-Seok Lee, Yurngdong Jahng, Youngjoo Kwon, Younghwa Na*
Keywords: Thioxanthones, Topoisomerase II inhibition, Anti-cancer agents
DOI: https://doi.org/10.5012/bkcs.2008.29.2.471

Abstract | Full Text: PDF


475  

A Valence Control Method Based on a Pt-Aided Hydrogen Peroxide Treatment for Yielding Tetravalent Neptunium and Plutonium in Nitric Acid Solutions
Moo Yul Suh*, Chang Heon Lee, Byoung Chul Song, Myung Ho Lee, Sun Ho Han, Se Chul Sohn, Kwang Yong Jee
Keywords: Neptunium, Plutonium, Valence control, Hydrogen peroxide, UTEVA-resin
DOI: https://doi.org/10.5012/bkcs.2008.29.2.475

Abstract | Full Text: PDF


479  

Selective Reduction of Trigonellyl Group to the Corresponding Dihydropyridine in the Presence of Disulfide Group
Ho-Joon Park, Young-Gyun Shin, Sang-Hoo Park, Jiaxaing Wu, Nicholas Bodor, Sung-Hwa Yoon*
Keywords: Blood brain barrier, Trigonellyl group, Disulfide bond, 1-Benzyl-1,2-dihydroisonicotinamide
DOI: https://doi.org/10.5012/bkcs.2008.29.2.479

Abstract | Full Text: PDF


483  

Synthesis and X-ray Structure of Zn(II) Complex of N,N'-Bis(2-fluorobenzyl)-(R,R)-1,2-diaminocyclohexane and Application to Nitroaldol Reaction
Quang Trung Nguyen, Jong Hwa Jeong*
Keywords: Chiral Zn(II) complex, X-Ray structure, Nitroaldol reaction, (R)-1-Phenyl-2-nitroethanol
DOI: https://doi.org/10.5012/bkcs.2008.29.2.483

Abstract | Full Text: PDF


487  

Synthesis of Cyclic Compounds Having exo-Methylene Groups through the Diels-Alder Reactions of Vinyl Allenes Obtained from Propargyl Bromide and Indium
Kooyeon Lee, Phil Ho Lee*
Keywords: Diels-Alder reaction, Indium, exo-Methylene compound, Propargyl bromide, Vinyl allene
DOI: https://doi.org/10.5012/bkcs.2008.29.2.487

Abstract | Full Text: PDF


491  

Enantiomer Separation of N-Protected α-Amino Acids on Covalently Immobilized Cellulose Tris(3,5-chlorophenylcarbamate) Chiral Stationary Phase in HPLC
Jing Yu Jin, Wonjae Lee*
Keywords: Enantiomer separation, Chiral stationary phase, Chiralpak IC
DOI: https://doi.org/10.5012/bkcs.2008.29.2.491

Abstract | Full Text: PDF


494  

Photocatalytic Behavior of WO3/TiO2 in Decomposing Volatile Aldehydes
Ashok Kumar Chakraborty, Seung Yong Chai, Wan In Lee*
Keywords: Photocatalyst, WO3/TiO2, Formaldehyde, Acetaldehyde, Propionaldehyde
DOI: https://doi.org/10.5012/bkcs.2008.29.2.494

Abstract | Full Text: PDF


497  

A Fluorescent Confirmation Method for DNA Amplification in PCR through a Fluorescent Pyrophosphate Sensor
Dong-Hoon Lee, Jong-In Hong*
Keywords: DNA amplification, Fluorescence, PCR, PPi
DOI: https://doi.org/10.5012/bkcs.2008.29.2.497

Abstract | Full Text: PDF


499  

Self-Assembled Copper(I) Complexes of Symmetric Dithioether Ligands
Tae Ho Kim, Garam Park, Yong Woon Shin, Ki-Min Park, Myong Yong Choi, Jineun Kim*
Keywords: Copper(I) iodide, Coordination polymer, Dithioether ligand, Crystal structure, Luminescence
DOI: https://doi.org/10.5012/bkcs.2008.29.2.499

Abstract | Full Text: PDF


503  

Synthesis of Hierarchical Self-Assembled BaMoO4 Microcrystals
Eun-Kyoung Ryu, Young-Duk Huh*
Keywords: Hierarchical self-assembly, Morphology, BaMoO4
DOI: https://doi.org/10.5012/bkcs.2008.29.2.503

Abstract | Full Text: PDF


507  

Effects of Hydroxy and Methoxy Substituents on NMR Data in Flavonols
Eunjung Lee, Byoung-Ho Moon, Younghee Park, Sungwon Hong, Sunhee Lee, Younggiu Lee, Yoongho Lim*
Keywords: NMR, Hydroxymethoxyflavonol derivatives, Structure
DOI: https://doi.org/10.5012/bkcs.2008.29.2.507

Abstract | Full Text: PDF


511  

A Linear Trinuclear Copper(II) Complex Containing 4-Substituted (m-Phenol)-1,2,4-triazole: Synthesis, Crystal Structure, and Properties of Magnetism and Fluorescence
Xiu-Cheng Zhang, Yong-Hong Chen, Bing Liu*
Keywords: Copper(II), Crystal structure, 1,2,4-Triazole, Fluorescence, Magnetism
DOI: https://doi.org/10.5012/bkcs.2008.29.2.511

Abstract | Full Text: PDF


515  

A New Synthetic Route for Natural Products with the Pyranobenzophenone Moiety: Clusiacitran A, Vismiaphenone B, Isovismiaphenone B, and Myrtiaphenone B
Yong Rok Lee*, Jung Hee Kim, Chul Soon Yong, Jong Sub Im, Won Seok Lyoo
Keywords: Pyranobenzophenone, Clusiacitran A, Vismiaphenone B, Isovismiaphenone B, Myrtiaphenone B
DOI: https://doi.org/10.5012/bkcs.2008.29.2.515

Abstract | Full Text: PDF


519  

An Efficient Synthesis of Racemic Tolterodine
Joo Hi Kang, Jong Hyoup Lee, Young Jun Park, Kyoung Soo Kim*, Jae Yeol Lee*
Keywords: Tolterodine, Racemate
DOI: https://doi.org/10.5012/bkcs.2008.29.2.519

Abstract | Full Text: PDF