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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 27, Number 2
BKCSDE 27(2)
February 20, 2006 

 

169  

Chemical Vapor Deposition Polymerization of Poly(arylenevinylene)s and Applications to Nanoscience
Sung-Hoon Joo, Chun-Young Lee, Kyungkon Kim, Ki-Ryong Lee, Jung-Il Jin*
Keywords: Chemical vapor deposition polymerization, Poly(arylenevinylene), Nano object, Field emission, Photoconductivity
DOI: https://doi.org/10.5012/bkcs.2006.27.2.169

Abstract | Full Text: PDF


185  

Catalytic Oxidation of Benzophenone Hydrazone with Alumina-supported KMnO4 under Oxygen Atmosphere
Kang-Hyeok Lee, Kwang-Youn Ko*
Keywords: Oxidation, Hydrazone, Potassium permanganate, Supported reagent
DOI: https://doi.org/10.5012/bkcs.2006.27.2.185

Abstract | Full Text: PDF


187  

Unusual Reverse Photochromic Behavior of Indolinobenzospiropyran 6-Carboxylates in Aqueous Binary Solvents
Sam-Rok Keum*, Se-Jung Roh, Sang-Eun Kim, Sung-Hoon Lee, Chul-Hee Cho, Sung-Hoon Kim, Kwang-Nak Koh
Keywords: Thermo- and photochromic molecules, Aqueous binary solvent mixtures, Normal and reverse photochromism
DOI: https://doi.org/10.5012/bkcs.2006.27.2.187

Abstract | Full Text: PDF


189  

Tin-free Radical Allylation of α-Acetoxy Alkyl Xanthates. Routes to Homoallyl Alcohols and α,β-Unsaturated Ketones
Jin Young Lee, Sunggak Kim*
Keywords: Radical reaction, Allylation, Homoallyl alcohol, α,β-Unsaturated ketone
DOI: https://doi.org/10.5012/bkcs.2006.27.2.189

Abstract | Full Text: PDF


191  

Highly Efficient Synthesis of 2-Aryl-3-methoxyacrylates via Suzuki-Miyaura Coupling Reaction
Hyung Ho Kim, Chun Ho Lee, Young Seob Song, No Kyun Park, Bum Tae Kim, Jung-Nyoung Heo*
Keywords: Suzuki reaction, Palladium, Boronic acid, Methoxyacrylate, Fungicide
DOI: https://doi.org/10.5012/bkcs.2006.27.2.191

Abstract | Full Text: PDF


193  

Synthesis and Characterization of High-Spin Cobalt(II)-Based “Inorgainc Tennis Ball”
Jung Su Park, Tae-Jin Park, Ki-Hyun Kim, Kyungeun Oh, Mi-Sook Seo, Hong-In Lee, Moo-Jin Jun, Wonwoo Nam*, Kwan Mook Kim*
Keywords: Inorganic tennis ball, Anion encapsulation, Self-assembly, High-spin cobalt
DOI: https://doi.org/10.5012/bkcs.2006.27.2.193

Abstract | Supporting Information | Full Text: PDF


195  

Electro Organic Synthesis Utilizing Mg Electrodes (II) - Novel Synthesis of Symmetric Azobenzenes from Nitrobenzenes -
Soonki Won, Wanjoong Kim, Hongbum Kim*
Keywords: Electro organic synthesis, Electro reductive coupling, Mg electrode, Azo compounds
DOI: https://doi.org/10.5012/bkcs.2006.27.2.195

Abstract | Full Text: PDF


197  

Reversible Excited-State Proton Transfer: Effect of the Switching of Interaction Potential by Reaction
Jinuk Lee, Jesik Uhm, Woojin Lee, Sangyoub Lee*, Jaeyoung Sung*
Keywords: Excited-state proton transfer, Reversible diffusion-influenced reaction, Effects of reactant force field
DOI: https://doi.org/10.5012/bkcs.2006.27.2.197

Abstract | Full Text: PDF


203  

Syntheses and Crystal Structures of Xylyl-Bridged NO2S2-Donor Macrocycles and Binuclear Mercury(II) Complex
Ji-Eun Lee, Yongri Jin, Joobeom Seo, Il Yoon, Mi Ryoung Song, So Young Lee, Ki-Min Park, Shim Sung Lee*
Keywords: Dilinked macrocycles, Crystal structure, Binuclear Hg(II) complex, Exo-coordination
DOI: https://doi.org/10.5012/bkcs.2006.27.2.203

Abstract | Full Text: PDF


208  

Using the New Developed Equation to Reproduce the Enthalpies of Transfer of Urea from Water to Aqueous Ethanol, Propan-1-ol and Acetonitrile at 298 K
G. Rezaei Behbehani*, E. Tazikeh, A. A. Saboury
Keywords: Micro calorimeter, Preferential solvation, Urea, Variable (αn + βN)
DOI: https://doi.org/10.5012/bkcs.2006.27.2.208

Abstract | Full Text: PDF


211  

QSPR Models for Chromatographic Retention of Some Azoles with Physicochemical Properties
Yulia Polyakova, Long Mei Jin, Kyung Ho Row*
Keywords: Nitrogen-containing heterocycles, Retention factor, QSPR, Correlation
DOI: https://doi.org/10.5012/bkcs.2006.27.2.211

Abstract | Full Text: PDF


219  

Thermal Decomposition of Tetrakis(ethylmethylamido) Titanium for Chemical Vapor Deposition of Titanium Nitride
Seong Jae Kim, Bo-Hye Kim, Hee-Gweon Woo, Su-Kyung Kim, Do-Heyoung Kim*
Keywords: Chemical vapor deposition (CVD), Tetrakis(ethylmethylamido) titanium (TEMAT), Titanium nitride, Film, Thermal decomposition
DOI: https://doi.org/10.5012/bkcs.2006.27.2.219

Abstract | Full Text: PDF


224  

Presteady State Kinetics of ATP Hydrolysis by Escherichia coli Rho Protein Monitors the Initiation Process
Yong-Joo Jeong, Dong-Eun Kim*
Keywords: E. coli transcription termination factor Rho, Presteady state kinetics, Global fit, Rapid-equilibrium, Chemical quenched-flow technique
DOI: https://doi.org/10.5012/bkcs.2006.27.2.224

Abstract | Full Text: PDF


231  

Headspace Hanging Drop Liquid Phase Microextraction and Gas Chromatography-Mass Spectrometry for the Analysis of Flavors from Clove Buds
Mi-Jin Jung, Yeon-Jae Shin, Se-Yeon Oh, Nam-Sun Kim, Kun Kim, Dong-Sun Lee*
Keywords: Headspace hanging drop liquid phase microextraction (HS-LPME), Gas chromatography-mass spectrometry (GC-MS), Sample pretreatment, Clove flavor
DOI: https://doi.org/10.5012/bkcs.2006.27.2.231

Abstract | Full Text: PDF


237  

Synthesis of Magnetic Nanoparticles of Fe3O4 and CoFe2O4 and Their Surface Modification by Surfactant Adsorption
Shi-Yong Zhao, Don Keun Lee, Chang Woo Kim, Hyun Gil Cha, Young Hwan Kim, Young Soo Kang*
Keywords: Magnetic nanoparticles, Surfactant adsorption, Fe3O4, CoFe2O4
DOI: https://doi.org/10.5012/bkcs.2006.27.2.237

Abstract | Full Text: PDF


243  

Mixed Intramolecular Hydrogen Bonding in Dihydroxythiophene-based Units and Boron and Technetium Chelation
Sangwon Ko, Sang Hyun Park, Hui Jeong Gwon, Junseong Lee, Min Jeong Kim, Yeonju Kwak, Youngkyu Do, David G. Churchill*
Keywords: Dihydroxythiophene, Hydrogen bonding, Boron chelation, Technetium-99m chelation, 99mTc tricarbonyl
DOI: https://doi.org/10.5012/bkcs.2006.27.2.243

Abstract | Full Text: PDF


251  

SANS Studies on the Formation of PANI Nanoparticles in the Reverse Micelles
Jae-Hyun Sim, Myungwoong Kim, Sangwook Park, Jeong Hwan Bang, Daewon Sohn*
Keywords: SANS, PANI, Nanoparticles, Micelle, Core-shell
DOI: https://doi.org/10.5012/bkcs.2006.27.2.251

Abstract | Full Text: PDF


255  

The Oxidation of Hydrazobenzene Catalyzed by Cobalt Complexes in Nonaqueous Solvents
Stephen S. B. Kim*, Roger B. Hommer, Roderick D. Cannon
Keywords: Catalytic cycle, Cobalt complexes, Hydrazobenzene, Axial ligands, Reaction mechanisms
DOI: https://doi.org/10.5012/bkcs.2006.27.2.255

Abstract | Full Text: PDF


266  

Quantitative Structure-Activity Relationships and Molecular Docking Studies of P56 LCK Inhibitors
Nagakumar Bharatham, Kavitha Bharatham, Keun Woo Lee*
Keywords: P56 LCK, Protein tyrosine kinase (PTKs), Benzothiazole derivatives, 3D-QSAR, GOLD molecular docking
DOI: https://doi.org/10.5012/bkcs.2006.27.2.266

Abstract | Full Text: PDF


273  

3D-QSAR of Non-peptidyl Caspase-3 Enzyme Inhibitors Using CoMFA and CoMSIA
Do Young Lee, Kwan Hoon Hyun, Hyung Yeon Park, Kyung A Lee, Bon-Su Lee, Chan Kyung Kim*
Keywords: CoMFA, CoMSIA, 3D-QSAR, Caspase-3 inhibitors
DOI: https://doi.org/10.5012/bkcs.2006.27.2.273

Abstract | Full Text: PDF


277  

Quantitative Determination of Nicotine in a PDMS Microfluidic Channel Using Surface Enhanced Raman Spectroscopy
Jaehyun Jung, Jaebum Choo*, Duck Joong Kim, Sanghoon Lee
Keywords: Surface enhanced Raman spectroscopy, Microfluidic chip, Nicotine, Quantitative analysis
DOI: https://doi.org/10.5012/bkcs.2006.27.2.277

Abstract | Full Text: PDF


281  

Development of Bipolar Plate Stack Type Microbial Fuel Cells
Seung-Hun Shin, Youngjin Choi, Sun-Hee Na, Seunho Jung*, Sunghyun Kim*
Keywords: Microbial fuel cell, Bipolar plate, Stack cell, Thionin, Proteus vulgaris
DOI: https://doi.org/10.5012/bkcs.2006.27.2.281

Abstract | Full Text: PDF


286  

Application of Microwave Activation Techniques to the N-Alkenyl Protection of Lactams
Ki Won Kim, Hee Sook Ahn, Ho Joon Lee, Suk Jin Song, Chung Gi Kim, Tae Woo Kwon*
Keywords: Pyrrolidin-2-one, Ethyl pyroglutamate, N-Alkenylation, Aldehyde condensation, Microwave irradiation
DOI: https://doi.org/10.5012/bkcs.2006.27.2.286

Abstract | Full Text: PDF


291  

High-Performance Liquid Chromatographic-Tandem Mass Spectrometric Determination of Itraconazole in Human Plasma for Bioavailability and Bioequivalence Studies
Young Wook Choi, Daeyoung Nam, Kyoung Hoon Kang, Kyung Wook Ha, In Hee Han, Byung Kon Chang, Mikyeong Yoon, Jaehwi Lee*
Keywords: High-performance liquid chromatography-tandem mass spectrometry, Itraconazole, Bioequivalence
DOI: https://doi.org/10.5012/bkcs.2006.27.2.291

Abstract | Full Text: PDF


295  

Photovoltaic Properties of Nano-particulate and Nanorod Array ZnO Electrodes for Dye-Sensitized Solar Cell
Ki Seok Kim, Yoon-Sik Kang, Jung-Hoon Lee, Yu-Ju Shin*, Nam-Gyu Park, Kwang Sun Ryu, Soon Ho Chang
Keywords: Nanocrystalline ZnO, Nanorod ZnO, Dye-sensitized solar cell
DOI: https://doi.org/10.5012/bkcs.2006.27.2.295

Abstract | Full Text: PDF


299  

Optical and Conformational Studies on (o-Tolyl)3PAuCl
Jun-Gill Kang*, Changmoon Park, Edward R. T. Tiekink
Keywords: (o-tolyl)3PAuCl, Reflection, Emission, CIS post-HF calculation, Charge transfer
DOI: https://doi.org/10.5012/bkcs.2006.27.2.299

Abstract | Full Text: PDF


302  

Sample Preparation for Headspace GC Analysis of Residual Solvents in Hyaluronic Acid Derivative Fiber
Hoonjoo Kim*, Dongmin Kim, Jeong Soo Yang, Chan-Wha Kim
Keywords: Headspace gas chromatography, Method validation, Residual solvent, Hyaluronic acid derivative, Hydrolysis
DOI: https://doi.org/10.5012/bkcs.2006.27.2.302

Abstract | Full Text: PDF


305  

Molecular Engineering. Part 12. Hemicarcerand Having a Metal Coordinating Ligand at a Hetero-Bridge
Byounghei Ye, Kyungsoo Paek*
Keywords: Hemicarcerand, Hemicarceplex, Metal coordination, Container dimer
DOI: https://doi.org/10.5012/bkcs.2006.27.2.305

Abstract | Full Text: PDF


309  

The Thermodynamics of Lanthanide-Pipecolinate Complexation in an Aqueous Solution
Sock-Sung Yun, Yunghee Oh, Me-A Kang, Young-Inn Kim*
Keywords: Thermodynamic parameters, Lanthanide complexes, Pipecolinate complex
DOI: https://doi.org/10.5012/bkcs.2006.27.2.309

Abstract | Full Text: PDF


312  

Synthesis of Isoeuparin and Isotubaic Acid
Yong Rok Lee*, Sang Heum Yoon
Keywords: Natural product, Isoeuparin, Isotubaic acid
DOI: https://doi.org/10.5012/bkcs.2006.27.2.312

Abstract | Full Text: PDF


315  

Selectivity of 12-Crown-4 to Cations in CH3OH: A Monte Carlo Simulation Study
Hag-Sung Kim
Keywords: The difference of stability constant of binding, Monte Carlo simulation, Selectivity
DOI: https://doi.org/10.5012/bkcs.2006.27.2.315

Abstract | Full Text: PDF


319  

Synthesis of Cyclopropane Derivatives Starting from the Baylis-Hillman Adducts Using Sulfur Ylide Chemistry
Ka Young Lee, Seung Chan Kim, Jae Nyoung Kim*
Keywords: Cyclopropane, Baylis-Hillman adducts, Sulfur ylide, Michael acceptor
DOI: https://doi.org/10.5012/bkcs.2006.27.2.319

Abstract | Full Text: PDF


322  

Effect of TiO2 Inclusion in the Poly(vinylidene fluoride-co-hexafluoropropylene)-Based Polymer Electrolyte of Dye-Sensitized Solar Cell
Kwang Man Kim*, Nam-Gyu Park, Man Gu Kang, Kwang Sun Ryu, Soon Ho Chang
Keywords: PVdF-HFP/TiO2, Polymer electrolytes, Dye-sensitized solar cell, Photovoltaic performance, Conversion efficiency
DOI: https://doi.org/10.5012/bkcs.2006.27.2.322

Abstract | Full Text: PDF


325  

Molecular Dynamics Simulations on the Coplanarity of Quercetin Backbone for the Antioxidant Activity of Quercetin-3-monoglycoside
Hyunmyung Kim, Karpjoo Jeong, Seunho Jung*
Keywords: Quercetin 3-monoglycoside, Flavonoid, Antioxidant activity, Coplanarity, Molecular dynamic simulations
DOI: https://doi.org/10.5012/bkcs.2006.27.2.325

Abstract | Full Text: PDF


329  

Enhancement of Nitrite Oxidation by Heat-Treated Cobalt Phthalocyanine Supported on High Area Carbon
Bong Yong Baik, Gwanghoon Kwag, Sunghyun Kim*
Keywords: Nitrite oxidation, Cobalt phthalocyanine, Heat-treatment, XANES, EXAFS
DOI: https://doi.org/10.5012/bkcs.2006.27.2.329

Abstract | Full Text: PDF


333  

(Schiff-Base)Mn(III)-Catalyzed Hydroxylation of α,β-Unsaturated Esters Using Molecular Oxygen in the Presence of Metal Hydrides
Jong Seok Baik, Sung-bin Han, Nam Ho Lee*
Keywords: Molecular oxygen, α,β-Unsaturated esters, Oxidation, (Schiff-Base)Mn(III), Hydroxylation
DOI: https://doi.org/10.5012/bkcs.2006.27.2.333

Abstract | Full Text: PDF