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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 26, Number 3
BKCSDE 26(3)
March 20, 2005 

 

361  

Biosurface Organic Chemistry: Interfacial Chemical Reactions for Applications to Nanobiotechnology and Biomedical Sciences
Young Shik Chi, Jungkyu K. Lee, Kyung-Bok Lee, Dong Jin Kim, Insung S. Choi*
Keywords: Biosurface organic chemistry, Surface organic chemistry, Self-assembled monolayers, Surfaceinitiated polymerization, Micropatterns
DOI: https://doi.org/10.5012/bkcs.2005.26.3.361

Abstract | Full Text: PDF


371  

Synthesis and Antibacterial Activity of 1,8-Naphthyridine Cephalosporins
Jong-Kyu Park, Sun-Kwon Im, Hyun Ju, Jae-Man Jeon, Chun-Gyu Kim, Dong-Uk Kim, Jin-Cheol Yoo, Seung-Sik Cho, Sung-Ki Cho*
Keywords: Cephalosporins, β-Lactam, Antibiotics, Naphthyridine
DOI: https://doi.org/10.5012/bkcs.2005.26.3.371

Abstract | Full Text: PDF


373  

Polymer-Supported Chiral Phosphinooxazolidine Ligands for Pd-catalyzed Asymmetic Allylic Substitution
Young-Mok Kim, Myung-Jong Jin*
Keywords: Asymmetric catalysis, Allylic substitution, Polymer-supported ligand, Phosphinooxazolidine
DOI: https://doi.org/10.5012/bkcs.2005.26.3.373

Abstract | Full Text: PDF


375  

Novel Synthon of N-Boc-Phytosphingosine-3,4-thiocarbonate for the Synthesis of Sphingosine Derivatives
Bo Gan Song, Bum Suk Son, Min Jung Seo, Jung Ki Kim, Gehyeong Lee, Zaesung No, Hyoung Rae Kim*
Keywords: Sphingosine, N-Boc-Phytosphingosine-3,4-thiocarbonate, 3-Dehydroxy-phytosphingosine, 2-Amino-octadec-3-en-1-ol
DOI: https://doi.org/10.5012/bkcs.2005.26.3.375

Abstract | Full Text: PDF


377  

Lithium Diisobutylpiperidinohydroaluminate (LDBPA) as a Mild and Efficient Reducing Agent for the Conversion of Ester to Aldehyde
Jin Hee Ahn, Jeong In Song, Jeong Eun Ahn, Duk Keun An*
Keywords: Lithium diisobutylpiperidinohydroaluminate (LDBPA), Diisobutylaluminium hydride, Aldehyde, Partial reduction, Piperidine
DOI: https://doi.org/10.5012/bkcs.2005.26.3.377

Abstract | Full Text: PDF


379  

Hybridization by an Electrical Force and Electrochemical Genome Detection Using an Indicator-free DNA on a Microelectrode-array DNA Chip
Yong-Sung Choi*, Kyung-Sup Lee, Dae-Hee Park
Keywords: Indicator-free DNA chip, Immobilization, Target DNA, Hybridization, Ferricyanide
DOI: https://doi.org/10.5012/bkcs.2005.26.3.379

Abstract | Full Text: PDF


384  

Study of Kinetics of Bromophenol Blue Fading in Alcohol-Water Binary Mixtures by SESMORTAC Model
Babak Samiey*, Kamal Alizadeh, Mir Fazlolah Mousavi, Nader Alizadeh
Keywords: SESMORTAC model, Kinetics, Alcohol, Bromophenol blue, Binary mixture
DOI: https://doi.org/10.5012/bkcs.2005.26.3.384

Abstract | Full Text: PDF


393  

Diaza-18-crown-6 Ethers Containing Partially-fluorinated Benzyl Sidearms: Effects of Covalently Bonded Fluorine on the Alkali Metal Complexation
Ki-Whan Chi*, Kwang Taeg Shim, Hwang Huh, Uk Lee, Young Ja Park
Keywords: Diaza-18-crown-6 ethers, Partially-fluorinated benzyl sidearms, Alkali metal cation complexation, Stability constant
DOI: https://doi.org/10.5012/bkcs.2005.26.3.393

Abstract | Full Text: PDF


399  

Optimization of Neural Networks Architecture for Impact Sensitivity of Energetic Molecules
Soo Gyeong Cho*, Kyoung Tai No*, Eun Mee Goh, Jeong Kook Kim, Jae Hong Shin, Young Dae Joo, Seeyearl Seong
Keywords: Energetic molecule, Explosives, Impact sensitivity, Neural networks, Molecular descriptor
DOI: https://doi.org/10.5012/bkcs.2005.26.3.399

Abstract | Full Text: PDF


409  

Novel Fabrication of Nanoporous Alumina Membrane Microtubes: 2-Dimensional Nanoporous Arrays on Every Facets of Microtubes
Weon-Sik Chae, Sung-Jae Im, Jin-Kyu Lee, Yong-Rok Kim*
Keywords: Nanoporous, Anodic alumina, Microtube, Rectangular, Cylindrical
DOI: https://doi.org/10.5012/bkcs.2005.26.3.409

Abstract | Full Text: PDF


413  

Fluorescence Quenching of Green Fluorescent Protein during Denaturation by Guanidine
Kichul Jung, Jaebok Park, Pil-Jae Maeng, Hackjin Kim*
Keywords: GFP, Fluorescence, Denaturation, Quencher
DOI: https://doi.org/10.5012/bkcs.2005.26.3.413

Abstract | Full Text: PDF


418  

Derivation of Cubic and Hexagonal Mesoporous Silica Films by Spin-coating
Jia Hong Pan, Wan In Lee*
Keywords: SiO2, Thin films, Mesoporous structure, Mesopore, EISA
DOI: https://doi.org/10.5012/bkcs.2005.26.3.418

Abstract | Full Text: PDF


423  

The Synergistic Effect of Organophosphorus and Dithiocarbamate Ligands on Metal Extraction in Supercritical CO2
Moonsung Koh, Kwangheon Park*, Doohyun Yang, Hakwon Kim, Hongdoo Kim*
Keywords: Supercritical, Carbon dioxide, Metal extraction, Synergistic effect, Amine
DOI: https://doi.org/10.5012/bkcs.2005.26.3.423

Abstract | Full Text: PDF


428  

The Novel Functional Chromophores Based on Squarylium Dyes
Soo-Youl Park*, Kun Jun, Sea-Wha Oh
Keywords: Squarylium, Monoanion, Dianion, Bathochromic shift
DOI: https://doi.org/10.5012/bkcs.2005.26.3.428

Abstract | Full Text: PDF


433  

Functional Studies of Tyrosine 108 Residue in the Active Site of Human Glutathione S-Transferase P1-1
Hee-Joong Park, Jong-Uk Koh, So-Youn Ahn, Kwang-Hoon Kong*
Keywords: Tyrosinase 108 residue, Enzymatic properties, Glutathione S-transferase, Substrate specificity
DOI: https://doi.org/10.5012/bkcs.2005.26.3.433

Abstract | Full Text: PDF


440  

Determination of Dibutyltin in Sediments Using Isotope Dilution Liquid Chromatography-Inductively Coupled Plasma Mass Spectrometry
Yong-Hyeon Yim*, Ji Youn Park, Myung Sub Han, Mi-Kyung Park,
Keywords: Organotin, Dibutyltin, Speciation, Isotope dilution, LC-ICP/MS
DOI: https://doi.org/10.5012/bkcs.2005.26.3.440

Abstract | Full Text: PDF


447  

Tsaokoarylone, a Cytotoxic Diarylheptanoid from Amomum tsao-ko Fruits
Surk-Sik Moon*, Soon-Chang Cho, Ji-Young Lee
Keywords: Amomum tsao-ko, Tsaokoarylone, Cytotoxicity, Curcumin, Diarylheptanoid
DOI: https://doi.org/10.5012/bkcs.2005.26.3.447

Abstract | Full Text: PDF


451  

Matrix Metalloproteinase-1 Inhibitor from the Aerial Parts of Viola ibukiana MAKINO
Hyung-In Moon*, Ji Eun Kim, Joongku Lee, Ok-Pyo Zee, Jin Ho Chung*
Keywords: Viola ibukiana, Matrix metalloproteinase-1, Ultraviolet irradiation, Phenolic
DOI: https://doi.org/10.5012/bkcs.2005.26.3.451

Abstract | Full Text: PDF


454  

(Schiff Base)Mn(III)-Catalyzed Oxidation of Benzylic Hydrocarbons Using Iodosobenzene as the Oxidant
Nam Ho Lee*, Jong Chul Byun, Tae-Heon Oh
Keywords: Benzylic oxidation, Mn(Schiff Base) complex, Iodosobenzene
DOI: https://doi.org/10.5012/bkcs.2005.26.3.454

Abstract | Full Text: PDF


457  

Effect of Changing Electrophilic Center from Carbonyl to Sulfonyl Group on Electrophilicity
Ik-Hwan Um*, Sun-Mee Chun, Sun-Kun Bae
Keywords: Nucleophilicity, Electrophilicity, Brønsted-type plot, Regioselectivity, Second-order rate constant
DOI: https://doi.org/10.5012/bkcs.2005.26.3.457

Abstract | Full Text: PDF


461  

Ti-Catalyzed Selective Isomerization of Terminal Mono-substituted Olefins
Hyung Soo Lee*, Gab Yong Lee
Keywords: Isomerization, Olefin, Catalyst, Cp2TiCl2, Selectivity
DOI: https://doi.org/10.5012/bkcs.2005.26.3.461

Abstract | Full Text: PDF


463  

Self-Assembled Monolayers of Azobenzene-Incorporated Alkanethiol on Silver
Sang Woo Han
Keywords: Azobenzene, Self-assembled monolayers, Silver, RAIR
DOI: https://doi.org/10.5012/bkcs.2005.26.3.463

Abstract | Full Text: PDF


467  

Synthesis of 2-Pyrazoline-5-Carboxylic Acid Derivatives Using Trimethylsilyldiazomethane
Jin Hee Ahn*, Hye-Min Kim, Seung Kyu Kang, Jae Du Ha, Eul Kgun Yum, Duk Keun An, Joong-Kwon Choi, Sung Soo Kim
Keywords: 2-Pyrazoline-5-carboxylic acid derivatives, [2+3] Cycloaddition, Trimethylsilyldiazomethane
DOI: https://doi.org/10.5012/bkcs.2005.26.3.467

Abstract | Full Text: PDF


470  

Synthesis, X-ray Structure and Anion Binding Properties of the Novel Urea Derivatives of Calix[4]arene Dimer
Eun Jin Cho, Byung Ju Ryu, Hyoung Min Yeo, Young Ju Lee, Kye Chun Nam*
Keywords: Calix[4]arene dimer, Anion receptor, Bridged urea derivative
DOI: https://doi.org/10.5012/bkcs.2005.26.3.470

Abstract | Full Text: PDF


473  

Discrete and Infinite Cyclic Dimer M(II) Complexes (M = Co, Zn) Based on Angular Dipyridyl Ligands Incorporating an Amide Spacer
Yong Woon Shin, Tae Ho Kim, Kang Yeol Lee, Ki-Min Park, Sang Woo Han, Shim Sung Lee, Jae Sang Kim, Jineun Kim*
Keywords: Crystal structure, Looped coordination polymer, Co(II), Zn(II), Hydrogen bonding
DOI: https://doi.org/10.5012/bkcs.2005.26.3.473

Abstract | Full Text: PDF


477  

Synthesis of N-Benzyl 3,5-Disubstituted Piperidines via Double Michael Addition Strategy
Mi Jung Lee, Ka Young Lee, Jae Nyoung Kim*
Keywords: 3,5-Disubstituted piperidine, Michael addition, Baylis-Hillman reaction
DOI: https://doi.org/10.5012/bkcs.2005.26.3.477

Abstract | Full Text: PDF


481  

Synthesis of Substituted Uracil Derivatives from the Acetates of the Baylis-Hillman Adducts
Chang Gon Lee, Saravanan Gowrisankar, Jae Nyoung Kim*
Keywords: Uracils, Baylis-Hillman adducts, DABCO
DOI: https://doi.org/10.5012/bkcs.2005.26.3.481

Abstract | Full Text: PDF


485  

Synthesis of Indeno[1,2-b]quinolin-10-ones via Pd/C-Assisted Dehydrogenation of 4b,5,10a,11-Tetrahydroindeno[1,2-b]quinolin-10-ones
Chang Gon Lee, Ka Young Lee, Seung Chan Kim, Jae Nyoung Kim*
Keywords: Indeno[1,2-b]quinolin-10-ones, Pd/C, Dehydrogenation, Baylis-Hillman adducts
DOI: https://doi.org/10.5012/bkcs.2005.26.3.485

Abstract | Full Text: PDF


488  

Polyboration Reaction of 1,1-Diethynyl-1-silacyclopent-3-ene with Boranes
Myung Hwa Kim, Young Tae Park*
Keywords: Polycarbosilane, Polyboration, Silacyclopent-3-ene, Boranes, Electronic and thermal properties
DOI: https://doi.org/10.5012/bkcs.2005.26.3.488

Abstract | Full Text: PDF


493  

A Catalytic 2-Aminoethanethiol Reduction on a Gold Electrode through a Sulfur-Gold Bond Formation
Hyosul Shin, Chan Kang*
Keywords: 2-Aminoethanethiol, Self assembled monolayer, Reductive desorption, Catalytic reduction
DOI: https://doi.org/10.5012/bkcs.2005.26.3.493

Abstract | Full Text: PDF


496  

Indium-Mediated Allylation of Hydroxyphthalides with Acetic Acid as an Additive
Ji Hee Lee, Young Sang Park, Mi Hye Nam, Seung Hwan Lee, Min Young Cho, Cheol Min Yoon*
Keywords: Indium, Acetic acid, Allylation, Hydroxyphthalides
DOI: https://doi.org/10.5012/bkcs.2005.26.3.496

Abstract | Full Text: PDF


499  

Oxidative Coupling of Benzylamines into N-Benzylbenzaldimines with Mn(II)/tert-BuOOH
Sung Soo Kim*, Santosh S. Thakur, Ji Young Song, Keun-Hyeung Lee
Keywords: Benzylamines, N-Benzylbenzaldimine, Electron transfer, Deprotonation, Oxidation
DOI: https://doi.org/10.5012/bkcs.2005.26.3.499

Abstract | Full Text: PDF