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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 26, Number 10
BKCSDE 26(10)
October 20, 2005 

 

1481  

Baylis-Hillman Reaction and Chemical Transformations of Baylis-Hillman Adducts
Ka Young Lee, Saravanan Gowrisankar, Jae Nyoung Kim*
Keywords: Baylis-Hillman reaction, Baylis-Hillman adducts, Chemical transformations
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1481

Abstract | Full Text: PDF


1491  

Facile Preparation of Trimethylsulfonium Bromide
Koon Ha Park*, Myung Sub So, Yong Whan Kim*
Keywords: Kornblum oxidation, Trimethylsulfonium bromide, Dimethyl sulfoxide, Benzyl bromide
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1491

Abstract | Full Text: PDF


1493  

Efficient Preparations of α-Azidoketones and α-Thiocyanatoketones via α-Sulfonyloxy Aryl Ketone Intermediates in Ionic Liquid
Jong Chan Lee*, Jin Seo Lee
Keywords: Azides, Hypervalent iodine, Ionic liquid, Ketones
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1493

Abstract | Full Text: PDF


1495  

Mild and Efficient Deoxygenation of Epoxides with Bis(cyclopentadienyl)titanium(IV) Dichloride-Indium System
Kwang Hyun Choi, Kyung Il Choi, Joong Hyup Kim, Cheol Min Yoon, Byung Woo Yoo*
Keywords: Epoxides, Deoxygenation, Indium, Titanium
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1495

Abstract | Full Text: PDF


1497  

Studies on the Total Synthesis of Amphidinolide O (II): A Stereoselective Synthesis of C1-C11 Fragment
Mi-Yeon Jang, Jong-Woo Kim, Duck-Hyung Lee*
Keywords: Amphidinolide O, Cytotoxic macrolide, Stereoselective synthesis, 1,5-anti-Selective aldol reaction, 1,3-anti-Selective reduction of β-hydroxy ketone
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1497

Abstract | Full Text: PDF


1499  

A Colorimetric and Fluorometric Chemosensor Based on Quinizarin-Metal Complexes for Alkaline Phosphatase Activity
Yong-Goo Son, Cheol Hee Lee, Ji-Soo Seo, Bum Jun Park, Jong-Man Kim*
Keywords: Chemosensor, Alkaline phosphatase, Quinizarin, Color and fluorescence
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1499

Abstract | Full Text: PDF


1501  

Catalytic Enantioselective Diethylzinc Addition to N-Phosphinoylimine Using Thiophosphoramide of Homologated Binaphthyl N,O-Ligand
Byeong-Seon Kim, Seung-Wan Kang, Kyoung Hoon Kim, Dong-Hyun Ko, Yongseog Chung, Deok-Chan Ha*
Keywords: Asymmetric synthesis, Chiral ligand, Diethylzinc, Imine, Catalyst
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1501

Abstract | Full Text: PDF


1503  

New Synthetic Approach to the Bicyclo[3.1.0]hexane Ring System from (+)-(1R,4R)-4-(Benzyloxymethyl)-4-(hydroxymethyl)cyclopent-2-enol
Soon-Ai Kim, Kenneth A. Jacobson, Hak Sung Kim*
Keywords: Bicyclo[3.1.0]hexane, Northern nucleoside, Adenosine receptor agonists, Antagonists
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1503

Abstract | Full Text: PDF


1505  

Excitation Energy Transfer Rate Constants in meso-meso Linked Zn(II) Porphyrin Arrays with Energy Accepting 5,15-Bisphenylethynylated Zn(II) Porphyrin
Damee Ko, Heeyoung Kim, Jin Hee Park, Dongho Kim*, Eunji Sim*
Keywords: Porphyrin, Energy transfer, Path integral, Simulation
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1505

Abstract | Full Text: PDF


1512  

Selective Hydrogenation of 1,3-Butadiene over Supported Nickel Catalyst Obtained from Nickel-Zirconia Solid Solution
Jong-San Chang*, Jae Oak Ryu, Jong Min Lee, Sang-Eon Park*, Do-Young Hong, Sung Hwa Jhung
Keywords: Ni-ZrO2, Solid solution, Selective hydrogenation
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1512

Abstract | Full Text: PDF


1515  

Photoinduced Superhydrophilicity in TiO2 Thin Films Modified with WO3
Young Kyu Hwang, Kashinath Rangu Patil, Hye-Kyung Kim, Shivaram Dattatraya Sathaye, Jin-Soo Hwang, Sang-Eon Park*, Jong-San Chang*
Keywords: Hydrophilicity, Water contact angle, TiO2 thin films, WO3
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1515

Abstract | Full Text: PDF


1520  

Synthesis of Novel 4'α-Phenyl and 5'α-Methyl Branched Carbocyclic Nucleosides
Chang Hyun Oh, Joon Hee Hong*
Keywords: Carbocyclic nucleoside, Antiviral agents, [3,3]-Sigmatropic rearrangement, Ring-closing metathesis
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1520

Abstract | Full Text: PDF


1525  

A Novel Method for Preparing of Oxoruthenates Complexes: trans-[RuO3(OH)2]2-, [RuO4]-, (n-Pr4N)+[RuO4]- and [RuO4] and Their Use as
Abdel-Ghany F. Shoair
Keywords: Oxoruthenates, Oxidation, N-Methylmorpholine-N-oxide (NMO)
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1525

Abstract | Full Text: PDF


1529  

Flotation-Spectrophotometric Determination of Ag(I) at the 10-7 mol L-1 Level Using Iodide and Ferroin as an Ion-associate
Mohammad Saeid Hosseini*, Hamid Hashemi-Moghaddam
Keywords: Flotation-spectrophotometry, Ag(I) determination, Ferroin, Ion-associate
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1529

Abstract | Full Text: PDF


1533  

Simultaneous Quantitative Determination of Monosaccharides Including Fructose in Hydrolysates of Yogurt and Orange Juice Products by Derivatization of Monosaccharides with p-Aminobenzoic Acid Ethyl Ester Followed by HPLC
Joung Ho Ko, Huazi Huang, Gyoung Won Kang, Won Jo Cheong*
Keywords: Monosaccharides, Reductive amination, p-Aminobenzoic acid ethyl ester, HPLC
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1533

Abstract | Full Text: PDF


1539  

Polyelectrolyte Micropatterning Using Agarose Plane Stamp and a Substrate Having Microscale Features on Its Surface
Min Jung Lee, Nae Yoon Lee, Sang Kil Lee, Sungsu Park, Youn Sang Kim*
Keywords: Micropatterning, Polyelectrolyte, Polymer on polymer stamping, Protein patterning, Surface chemistry
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1539

Abstract | Full Text: PDF


1543  

Synthesis and Structure of Sr6Ge5N2 and Ba6Ge5N2
Dong Gon Park*, Zoltan A. Gal, Francis J. DiSalvo
Keywords: Strontium germanium nitride, Barium germanium nitride, Zintl anion
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1543

Abstract | Full Text: PDF


1549  

Chiral Separation of Arylalcohols by Capillary Electrophoresis Using Sulfonated β-Cyclodextrin and Ag Colloids as Additives
Seong-Ho Choi*, Hyen-Ju Noh, Kwang-Pill Lee
Keywords: Capillary electrophoresis, Ag colloid, γ-Irradiation, Sulfonated β-cyclodextrin
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1549

Abstract | Full Text: PDF


1555  

Highly Sensitive Fluorescence Probes for Organic Vapors: On/off and Dual Color Fluorescence Switching
Byeong-Kwan An, Soon-Ki Kwon, Soo Young Park*
Keywords: Fluorescent probe, Volatile organic compounds (VOCs), Chemosensor, Aggregation-induced enhanced emission (AIEE)
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1555

Abstract | Full Text: PDF


1560  

Voltammetric Determination of Bisphenol A Using a Carbon Paste Electrode Based on the Enhancement Effect of Cetyltrimethylammonium Bromide (CTAB)
Wensheng Huang
Keywords: Surfactant, Enhancement effect, Bisphenol A, Electrochemical detection, Carbon paste electrode
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1560

Abstract | Full Text: PDF


1565  

Surface Renewable Hydrogen Ion-Selective Polymeric Composite Electrode Containing Iridium Oxide
Hongmei Quan, Won Kim, Koo-Chun Chung, Jongman Park*
Keywords: Hydrogen ion selective electrode, Composite electrode, Iridium oxide
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1565

Abstract | Full Text: PDF


1569  

Synthesis of 5,6-Dihydro[1,10]phenanthroline Derivatives and Their Properties as Hole-Blocking Layer Materials for Phosphorescent Organic Light-Emitting Diodes
Hyo Won Lee*, Jung-Gi An, Hee-Kyoon Yoon, Hyosook Jang, Nam Gwang Kim, Youngkyu Do*
Keywords: BCP derivatives, 5,6-Dihydro-2,9-diisopropyl-4,7-diaryl[1,10]phenanthroline, Hole-blocking materials, Phosphorescent organic light-emitting diode
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1569

Abstract | Full Text: PDF


1575  

Synthesis, Crystal Structure and Luminescence Property of a New Silver(I) Dimer with Isonicotinic Acid
Qi Yuan, Bing Liu*
Keywords: Silver, Isonicotinic acid, Crystal structure, Luminescence
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1575

Abstract | Full Text: PDF


1579  

CdS Coating on TiO2 Nanoparticles under Multibubble Sonoluminescence Condition
Seung Soo Lee, Kook Won Seo, Seok Hwan Yoon, Il-Wun Shim*, Ki-Taek Byun, Ho-Young Kwak*
Keywords: CdS-coated TiO2 nanoparticles, MBSL (Multibubble sonoluminescence), Sonochemical reaction
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1579

Abstract | Full Text: PDF


1582  

Preparation of ZnS Thin Film Using Zn(dithiocarbamate)2 Precursors by MOCVD Method
Kook Won Seo, Seok Hwan Yoon, Seung Soo Lee, Il-Wun Shim*
Keywords: ZnS, Zinc sulfide thin film, Zinc dithiocarbamate, MOCVD, Buffer layer in solar cell
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1582

Abstract | Full Text: PDF


1585  

Cobalt Polyoxometalate, [CoW12O40]5-, as a New Reusable Catalyst for Addition of Trimethylsilyl Cyanide to Carbonyl Compounds
E. Rafiee*, Shahram Tangestaninejad, M. H. Habibi, V. Mirkhani
Keywords: Trimethylsilyl cyanide, TMSCN, Cyanohydrin trimethylsilyl, Polyoxometalate
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1585

Abstract | Full Text: PDF


1588  

Efficient Synthesis of (3S,4R)-(+)-3-Methyl-6-hepten-4-olide
Woosun Jun, Yunkyung Jeong, Ho-Jung Kang*
Keywords: Massarilactone A, γ-Butyrolactone, 3-Methyl-6-hepten-4-olide
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1588

Abstract | Full Text: PDF


1591  

Catalytic Activities of Perovskite-type LaBO3 (B = Fe, Co, Ni) Oxides for Partial Oxidation of Methane
Myung-Jin Lee, Jong-Ho Jun, Jin-Seung Jung, Yong-Rok Kim, Sung-Han Lee*
Keywords: Lanthanum-transition metal perovskite oxides, Partial oxidation of methane
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1591

Abstract | Full Text: PDF


1597  

Novel Synthesis of Chiral 5-Cyanomethyl-3,4-dihydroxy-2-iodomethyltetrahydrofuran from 3-Diphenylmethyl-5-(1,2-dihydroxy-3-butenyl)isoxazolines via Iodoetheration Reaction
Min Jung Seo, Bum Suk Son, Bo Gan Song, Bok Ju Song, Sang Dae Lee, Ji Young Kim, Hak Do Kim, Zaesung No, Hyoung Rae Kim*
Keywords: 5-Cyanomethyl-3,4-dihydroxy-2-iodomethyltetrahydrofuran, 1,3-Dipolar cycloaddition, Isoxazoline, Iodoetheration, Diastereoselectivity
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1597

Abstract | Full Text: PDF


1600  

Oxidative Coupling of Benzylamines into N-Benzylbenzaldimines with MnTPPCl/t-BuOOH
Sung Soo Kim*, Santosh S. Thakur
Keywords: Benzylamines, N-Benzylbenzaldimine, Electron transfer, Deprotonation, Coupling
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1600

Abstract | Full Text: PDF


1603  

Transition Metal Cluster Chalcogenide Ligated by Multiple Redox Active Organometallic Centers: [Ni63-Se)24-Se)3(dppf)3]Br2 and Its Electrocatalysis
Sam Gon Kim, Dong Hyun Kim, Dong Min Kang, Md. Abdul Jabbar, Kil Sik Min, Yoon-Bo Shim*, Sung Chul Shin*
Keywords: Transition metal cluster, Electrocatalysis, Organic/inorganic hybrids, Multi-metallocenyl assemblies
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1603

Abstract | Full Text: PDF


1607  

Photochemical Decomposition of Nalidixic Acid in Water
Ki-Min Bark, Yong-Sung Kim, Chul-Ho Park, Hyeong-Chul Lee, Hyoung-Ryun Park*
Keywords: Photochemical reaction, Nalidixic acid, 7-Methyl-4-oxo-2,4-dihydro-1H-8,8b-diaza-cyclobuta[a]naphthalene-3-carboxylic acid, 7-Methyl-4-oxo-1,4-dihydro-[1,8]naphthyridine-3-carboxylic acid, 1,7-Dimethyl-4-oxo-1,4-dihydro-[1,8]naphthyridine-3-carboxylic ac
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1607

Abstract | Full Text: PDF


1611  

Pd/C-Catalyzed Oxidative Alkylation of Secondary Alcohols with Primary Alcohols
Chan Sik Cho*, Wen Xiu Ren, Sang Chul Shim*
Keywords: Aldol reaction, Oxidative alkylation, Pd/C catalyst, Primary alcohols, Secondary alcohols
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1611

Abstract | Full Text: PDF


1614  

A Facile Synthesis of Anthranilic Acid-Derived N,N,O-Terdentates
Yurngdong Jahng*, Jason R. Telford
Keywords: N,N,O-Terdentate, Anthranilic acid, Arylamination, Ullmann reaction
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1614

Abstract | Full Text: PDF


1617  

Ring Opening Reaction of Epoxides under Aryl Acetylene/ZnBr2/DIEA Conditions
Ka Young Lee, Da Yeon Park, Taek Hyeon Kim, Jae Nyoung Kim*
Keywords: Epoxides, Aryl acetylene, ZnBr2, DIEA, Ring-opening
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1617

Abstract | Full Text: PDF


1620  

Syntheses and Crystal Structure of Cp*Ti(β-diketonato)Cl2 Complexes
Samkeun Lee*, Sung Kwon Kang*, Seung Jae Lee, Sock Sung Yun, Tae-Sun Chang
Keywords: Titanium(IV) complex, β-Diketonate, Pentamethylcyclopentadienyl, Crystal structure
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1620

Abstract | Full Text: PDF


1623  

Spectrophotometric Determination of Palladium by the Colouration with 2-(2-Quinolylazo)-5-diethylaminobenzoic Acid
Zhangjie Huang, Qunyan Wei, Xiangjun Yang, Qiufen Hu, Jing Chen, Guangyu Yang*
Keywords: 2-(2-Quinolylazo)-5-diethylaminobenzoic acid, Palladium, Spectrophotometry
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1623

Abstract | Full Text: PDF


1627  

Subtle Coligand Effects on Chelation of (Benzyl-1-propenylmalonato)platinum(II) Complexes
Young-A Lee
Keywords: Ambidentate ligand, Benzyl-1-propenylmalonate ligand, Coligand effect, Crystal structure, Platinum(II) complexes
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1627

Abstract | Full Text: PDF


1631  

Synthesis and Crystal Structures of Two Metal Complexes Incorporating Malonate and Organodiamine Ligands
Quan-Zheng Zhang, Wen-Bin Yang, Shu-Mei Chen, Can-Zhong Lu*
Keywords: Malonate, Organodiamine ligand, Crystal structure
DOI: https://doi.org/10.5012/bkcs.2005.26.10.1631

Abstract | Full Text: PDF