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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 25, Number 9
BKCSDE 25(9)
September 20, 2004 

 

1295  

Facile and Efficient Method for the Acetylation of Alcohols under Microwave Irradiation
Jong Chan Lee*, Seung Jun Lee, Jin Seo Lee
Keywords: Acylation, Alcohols, PPTS, Microwave, Solvent-free
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1295

Abstract | Full Text: PDF


1297  

Hydroxylated-Cpd 5: Possible ‘better’ Arylator on Cell Growth Inhibition
Seung Wook Ham*, Siyeon Lee
Keywords: Cdc25 phosphatase, Naphthoquinone, Cell growth inhibition, Reduction potential
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1297

Abstract | Full Text: PDF


1299  

Synthesis and Characterization of meso-Substituted Porphyrins Bearing 2,3-Dicyanopyraiznes
Bum-Hoon Lee, Jong-Ho Park, Jae-yun Jaung*
Keywords: Dicyanopyrazine, meso-Porphyrin, Absorption spectra, Q-band
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1299

Abstract | Full Text: PDF


1301  

Functionalization of Shortened SWCNTs Using Esterification
Wan-Joong Kim, Sung-Oong Kang, Chil Seong Ah, Yong-Won Lee, Dong Han Ha, Insung S. Choi*, Wan Soo Yun*
Keywords: Carbon nanotubes (CNTs), Functionalization, Esterification
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1301

Abstract | Full Text: PDF


1303  

Inhibition of Protein Tyrosine Phosphatase 1B by Aurintricarboxylic Acid and Methylenedisalicylic Acid; Polymer versus Monomer
Suja Shrestha, Keun-Hyeung Lee, Hyeongjin Cho*
Keywords: Protein tyrosine phosphatase, Aurintricarboxylic acid, Methylenedisalicylic acid, PTP1B, Inhibitor
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1303

Abstract | Full Text: PDF


1305  

Synthesis of Cyano Cyclic Olefins through Ring-Closing Metathesis
Ihl Young Choi*, Kyoung Hee Byoun, Myung Hee Jung, Hee-Jeong Lim, Hyo Won Lee
Keywords: Ring-closing metathesis, Microwave irradiation, Cyano cyclic olefins
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1305

Abstract | Full Text: PDF


1307  

Synthesis of Cyclic Peroxides via Enyne-RCM/Diels-Alder Reaction Sequence
Young-Keun Yang, Susie Lee, Jinsung Tae*
Keywords: Cyclic peroxides, Cyclic hydroxylamines, Diels-Alder reactions, Enyne metathesis, Singlet oxygen
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1307

Abstract | Full Text: PDF


1309  

Flame Atomic Absorption Spectrometric Determination of Ultra Traces of Thallium(I) ion after Solid Phase Extraction by Octadecyl Silica Membrane Disk Modified by a New Schiff Base
Mohammad Hossein Mashhadizadeh*, Ali Moatafavi, Hossein Allah-Abadi, Mohammad Reza Zadmehr
Keywords: Solid phase extraction, Thallium, Octadecyl silica, Schiff base
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1309

Abstract | Full Text: PDF


1314  

The Adsorptions and Configurations of CO Molecules on W (110) and W (100) Surface: Molecular Orbital Theory
Sang Joon Choe*, Hae Jin Kang, Dong Ho Park, Do Sung Huh, Soon-Bo Lee
Keywords: Adsorption of carbon monoxide, Tungsten
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1314

Abstract | Full Text: PDF


1321  

Square Wave Voltammetric Determination of Indole-3-acetic Acid Based on the Enhancement Effect of Anionic Surfactant at the Carbon Paste Electrode
Shenghui Zhang, Kangbing Wu*
Keywords: Indole-3-acetic acid, Surfactant effects, Carbon paste electrode, Voltammetric determination
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1321

Abstract | Full Text: PDF


1326  

Synthesis of Oxazolidinone Phosphonate Derivatives, Part I
Jae-Min Hwang, Woon-Seob Shin, Kang-Yeoun Jung*
Keywords: Oxazolidinone, Oxazolidinone phosphonates, Antibacterial agent, N-Arylation, γ-Ketophosphonate
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1326

Abstract | Full Text: PDF


1331  

Angiogenesis Inhibitor Derived from Angiostatin Active Sites
Kyoungsoo Park, Dongyeol Lim, Sang-Don Park, Min-Young Kim, Yangmee Kim*
Keywords: Angiogenesis inhibitor, Kringle, CAM assay, Peptidomimetics, Structure
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1331

Abstract | Full Text: PDF


1336  

Enantioseparation of Racemic 1,1\'-Binaphthyl-2,2\'-diamine by Preparative Liquid Chromatography
Jae Jeong Ryoo*, Woo Jeong Kwon, Tae Hyuk Kim, Kwang-Pill Lee, Seong-Ho Choi
Keywords: Preparative liquid chromatography, Chiral separation, N-Acetyl-1-naphthylethylamide, 1,1'-Binaphthyl-2,2'-diamine, Separation condition
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1336

Abstract | Full Text: PDF


1341  

Synthesis and Characterization of Highly Crystalline Anatase Nanowire Arrays
Yongnan Zhao, U-Hwang Lee, Myungkoo Suh, Young-Uk Kwon*
Keywords: Nanowire array, Anatase, Titanate, Hydrothermal synthesis
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1341

Abstract | Full Text: PDF


1346  

Stoichiometric Solvent Effect on SN1 Solvolytic Reactivity Accounting for Phenomenon of Maximum Rates in Methanol-Nitromethane Mixtures
Zoon Ha Ryu*, Su-Han Choi, Gui Taek Lim, Dea Dong Sung, T. William Bentley
Keywords: Solvolysis, Third order kinetic model, Isodielectric mixture, Solvent effect
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1346

Abstract | Full Text: PDF


1351  

Synthesis of Tetracyclic 5-Azaindole Analogues by Palladium-Catalyzed Sequential Annulation
Nack-Do Sung, Ok-Kyung Yang, Song Su Kang, Eul Kgun Yum*
Keywords: Tetracyclic 5-azaindole analogues, Palladium, Catalyst, Annulation, 1-Aryl alkynes
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1351

Abstract | Full Text: PDF


1355  

Catalytic Oxidation of Trichloroethylene over Pd-Loaded Sulfated Zirconia
Jung-Nam Park, Chul Wee Lee*, Jong-San Chang, Sang-Eon Park*, Chae-Ho Shin
Keywords: Trichloroethylene, Catalytic oxidation, Palladium, Sulfated zirconia
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1355

Abstract | Full Text: PDF


1361  

Solvatokinetic and Solvatochromic Behavior of Bis(indolinobenzospiropyranyl) Sulfide Derivatives in Various Solvents
Sam-Rok Keum*, Byung-Soo Ku, Sang-Eun Kim, Yoon-Ki Choi, Sung-Hoon Kim, Kwangnak Koh
Keywords: Solvatokinetic and solvatochromic behavior, Thermo- and photochromic dyes, Bis(indolinobenzospiropyranyl) sulfides, Dual mechanistic process, Biphasic plot
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1361

Abstract | Full Text: PDF


1366  

Effect of Linker for Immobilization of Glutathione on BSA-Assembled Controlled Pore Glass Beads
Li-Hua Chen, Young-Seo Choi, Jung Won Park, Joseph Kwon, Rong-Shun Wang, Taehoon Lee, Sung Ho Ryu, Joon Won Park*
Keywords: Glutathione (GSH), Glutathione-S-transferase (GST), Controlled pore glass (CPG), Linker, Bovine serum albumin (BSA)
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1366

Abstract | Full Text: PDF


1371  

Synthesis of Silica Membranes on a Porous Stainless Steel by Sol-Gel Method and Effect of Preparation Conditions on Their Permselectivity
Dong-Wook Lee, Seung-Eun Nam, Bongkuk Sea, Son-Ki Ihm, Kew-Ho Lee*
Keywords: Silica composite membrane, Sol-gel method, Hydrogen purification
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1371

Abstract | Full Text: PDF


1379  

Base-Catalyzed Rearrangement of Some 1,3-Oxathiolane Sulfoxides: Mechanistic Viewpoint of the Sigmatropic and Elimination Reactions
Hoh-Gyu Hahn*, Kee Dal Nam, Seung Hoon Cheon
Keywords: Sigmatropic rearrangement, Sulfoxide, Sulfenic acid, Thiolsulfinate, Sulfinic acid
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1379

Abstract | Full Text: PDF


1385  

A Convenient Synthesis of Optically Active Unhindered Aliphatic Alcohols with High Optical Purity from Non-Racemic β-Hydroxy Sulfides
Byung Tae Cho*, Dong Jun Kim
Keywords: Chiral aliphatic alcohols, Asymmetric reduction, (S)-CBS oxazaborolidine, Chiral β-hydroxy sulfides
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1385

Abstract | Full Text: PDF


1392  

SERS Analysis of CMC on Gold-Assembled Micelle
Nak Han Jang
Keywords: SERS, Cationic surfactant, CMC, Gold nanoparticles
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1392

Abstract | Full Text: PDF


1397  

Rotational State Distributions of I2(B) from Vibrational Predissociation of I2(B)-Ne
Sung-sil Cho, Hosung Sun*
Keywords: Vibrational predissociation, I2-Ne
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1397

Abstract | Full Text: PDF


1403  

Microwave Dielectric Characterization of Binary Mixtures of 3-Nitrotoluene with Dimethylacetamide, Dimethylformamide and Dimethylsulphoxide
Ajay Chaudhari*, H. C. Chaudhari, S. C. Mehrotra
Keywords: Dielectric relaxation, Mixture, Excess properties, Time domain reflectometry
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1403

Abstract | Full Text: PDF


1408  

Synthesis and Cytotoxicity of Anilinomethyl-1,4-naphthoquinones
Yongseog Chung*, Jong Kwan Im, Sungduck Lee, Hoon Cho*
Keywords: Anilinomethyl-1,4-naphthoquinone, Cytotoxicity
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1408

Abstract | Full Text: PDF


1411  

Molecular Tweezer Based on Chenodeoxycholic Acid:Synthesis, Anion Binding Properties
Ki Soo Kim, Hong-Seok Kim*
Keywords: Molecular tweezer, Chenodeoxycholic acid, Urea receptor, Anion recognition
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1411

Abstract | Full Text: PDF


1414  

Nitration of Aromatic Compounds on Silica Sulfuric Acid
Mohammad Ali Zolfigol*, BiBi Fatemeh Mirjalili, Abdolhamid Bamoniri, Mohammad Ali Karimi Zarchi, Amin Zarei, Leila Khazdooz, Jalil Noei
Keywords: Silica sulfuric acid, Sodium nitrate, Nitration, Solvent free conditions
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1414

Abstract | Full Text: PDF


1417  

Synthesis of Thiophene Derivatives of 1,3-Diazabicyclo[3,1,0]hex-3-ene
Nosrat O. Mahmoodi*, Hamzeh Kiyani
Keywords: Photochromism, Aziridine Ring, 2-Thiophen-2-yl, 1,3-Diazabicyclo[3,1,0]hex-3-ene derivatives, Intellegent material
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1417

Abstract | Full Text: PDF


1421  

Synthesis of Regioselectively Diiodinated Porphyrins; 5,20-Diaryl-12,13-diiodoporphyrins
Pradeepta K. Panda, Sasmita Padhy, Kwon-Soo Ha, Chang-Hee Lee*
Keywords: Diiodinated porphyrins, 3,4-Diiodo-2,5-bis(hydroxymethyl)pyrrole, ‘3+1’ condensation
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1421

Abstract | Full Text: PDF


1423  

Rapid Identification of Aliphatic Ketones from Vapor-Phase Infrared Spectra
Dongjin Pyo*, Jongchon Choi
Keywords: Computerized interpretation, Infrared spectra, Aliphatic ketone
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1423

Abstract | Full Text: PDF


1427  

First Hyperpolarizabilities of Nonlinear Optical Compounds: Susceptibility in Donor-Acceptor Stilbene Analogs
Gyoosoon Park, Woo Sik Jung, Choon Sup Ra*
Keywords: Nonlinear optical, Hyperpolarizability, Susceptibility, Heteroaromatics, Stilbene
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1427

Abstract | Full Text: PDF


1430  

Fluorescence Detection of Protein/Z-DNA Interactions
Dong Jin Kim, Doo-Byoung Oh, Seon Min Lee, Insung S. Choi*, Yang-Gyun Kim*
Keywords: Z-DNA, Z-DNA-binding protein, Glutathione S-transferase (GST), Polyvalency, Fluorescence detection
DOI: https://doi.org/10.5012/bkcs.2004.25.9.1430

Abstract | Full Text: PDF