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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 24, Number 5
BKCSDE 24(5)
May 20, 2003 

 

535  

Synthesis and Characterization of an Eight-Coordinated [Ho(hfa)2(triglyme)][Ho(hfa)4] Holmium Complex
Seong-Joo Kang, Sang Kwon Lee
Keywords: Holmium, Hexafluoropentanedione, Metal b-diketonates
DOI: https://doi.org/10.5012/bkcs.2003.24.5.535

Abstract | Full Text: PDF


537  

Asymmetric Alkene Epoxidations Catalyzed by Sterically Hindered Salen-Mn(III) Complexes
Yong-Chul Jeong, Sunho Choi, Kyunga Yu, Kwang-Hyun Ahn
Keywords: Asymmetric, Epoxidation, Salen, Enantioselectivity
DOI: https://doi.org/10.5012/bkcs.2003.24.5.537

Abstract | Full Text: PDF


539  

Studies on Reductive Pauson-Khand Reaction Using Cobaltcarbonyls with Water
Hee-Yoon Lee, Mihyun An, Jeong-Hun Sohn
Keywords: Pauson-Khand reaction, Reduction, Water
DOI: https://doi.org/10.5012/bkcs.2003.24.5.539

Abstract | Full Text: PDF


541  

A New Antitumor b-Dihydroagarofuran Sesquiterpene Polyol Ester from the Euonymus Nanoides
Hong Wang, Xuan Tian, Yuan-Jiang Pan
Keywords: Antitumor, Sesquiterpene, Euonymus nanoides
DOI: https://doi.org/10.5012/bkcs.2003.24.5.541

Abstract | Full Text: PDF


543  

Cu(I) Mediated Deamination of N-Boc Aryl Hydrazines and Its Mechanistical Implication
Young-Kwan Lim, Soo-Jin Pang, Seunguk Paik, Cheon-Gyu Cho
Keywords: Aryl hydrazide, Deamination, Cu(I)
DOI: https://doi.org/10.5012/bkcs.2003.24.5.543

Abstract | Full Text: PDF


545  

Computational Study of s- and p-type Hydrogen Bonding in Acetonitrile-Water Clusters
Doo-Sik Ahn, Sungyul Lee
Keywords: Hydrogen bonding, Cluster
DOI: https://doi.org/10.5012/bkcs.2003.24.5.545

Abstract | Full Text: PDF


547  

An Isothermal Titration Microcalorimetric Study on the Interaction of Three Water-Soluble Porphyrins with Histone H2B
A. K. Bordbar, A. R. Ghaderi, E. Safaei, S. Tangestaninejad, A. Eslami, A. A. Saboury, A. A. Moosavi-Movahedi
Keywords: Porphyrin, Histone (H2B), Isothermal titration microcalorimetry, Aggregation
DOI: https://doi.org/10.5012/bkcs.2003.24.5.547

Abstract | Full Text: PDF


552  

Single Nanoparticle Ion Trap (SNIT): A Novel Tool for Studying in-situ Dynamics of Single Nanoparticles
Sung Cheol Seo, Seung Kyun Hong, Doo Wan Boo
Keywords: Single nanoparticle, Ion trap, in-situ dynamics, Mass analysis
DOI: https://doi.org/10.5012/bkcs.2003.24.5.552

Abstract | Full Text: PDF


555  

Sorbent Extraction of Some Metal Ions on a Gas Chromatographic Stationary Phase Prior to Their Flame Atomic Absorption Determinations
M. Soylak, S. Saracoglu, L. Elci
Keywords: Trace metals, Impurities, Chromosorb-102, Preconcentration, Calmagite
DOI: https://doi.org/10.5012/bkcs.2003.24.5.555

Abstract | Full Text: PDF


559  

Studies on the Analysis of Benzo(a)pyrene and Its Metabolites in Biological Samples by Using High Performance Liquid Chromatograpy/Fluorescence Detection and Gas Chromatography/Mass Spectrometry
Won Lee, Hye Seung Shin, Jee Eun Hong, Heesoo Pyo, Yunje Kim
Keywords: Benzo(a)pyrene, Hydroxylated metabolites, Rat urine, Blood plasma, HPLC/FLD
DOI: https://doi.org/10.5012/bkcs.2003.24.5.559

Abstract | Full Text: PDF


566  

Cathodoluminescence Enhancement of CaTiO3:Pr3+ by Ga Addition
Seung-Youl Kang, Jung-Woo Byun, Jin Young Kim, Kyung-Soo Suh, Seong-Gu Kang†
Keywords: Field emission displays (FED), Cathodoluminescence intensity, Phosphors
DOI: https://doi.org/10.5012/bkcs.2003.24.5.566

Abstract | Full Text: PDF


569  

Synthesis of Merocyanines Analogues Based on the Pyrazolin-5-one System
Soo-Youl Park, Sea-Wha Oh
Keywords: Merocyanines, H-Chromophore, Pyrazolin-5-one, Bathochromism
DOI: https://doi.org/10.5012/bkcs.2003.24.5.569

Abstract | Full Text: PDF


573  

Metal-Insulator Transition Induced by Short Range Magnetic Ordering in Mono-layered Manganite
E. O. Chi, W. S. Kim, C. S. Hong, N. H. Hur, Y. N. Choi
Keywords: Magnetism, Manganese oxide, Magnetic ordering
DOI: https://doi.org/10.5012/bkcs.2003.24.5.573

Abstract | Full Text: PDF


579  

Interaction of Norfloxacin with Super-Coiled DNA
Hyun Jung Hwangbo, Young-Ae Lee, Jung Hag Park, Yong Rok Lee, Jong Moon Kim, Seh-Yoon Yi, Seog K. Kim
Keywords: Quinolone, Norfloxacin, DNA, Super-coiled DNA
DOI: https://doi.org/10.5012/bkcs.2003.24.5.579

Abstract | Full Text: PDF


583  

Theoretical Studies of the Gas-Phase Identity Nucleophilic Substitution Reactions of Cyclopentadienyl Halides
Ikchoon Lee, Hong Guang Li, Chang Kon Kim, Bon-Su Lee, Chan Kyung Kim, Hai Whang Lee
Keywords: Gas-phase, Nucleophilic substitution, Cyclopentadienyl halides, G2(+)MP2
DOI: https://doi.org/10.5012/bkcs.2003.24.5.583

Abstract | Full Text: PDF


593  

Nanoparticle Ferrite Multilayers Prepared by New Self-Assembling Sequential Adsorption Method
Yeong Il Kim, Hojun Kang, Don Kim, Choong Sub Lee
Keywords: Magnetite, Nanoparticle, Metal bisphosphonate, Self-assembly
DOI: https://doi.org/10.5012/bkcs.2003.24.5.593

Abstract | Full Text: PDF


600  

Simulation of Atom Focusing for Nanostructure Fabrication
Chang Jae Lee
Keywords: Atom lithography, Nanofabrication, Atom manipulation, Atom-laser interaction
DOI: https://doi.org/10.5012/bkcs.2003.24.5.600

Abstract | Full Text: PDF


605  

Synthesis and Characterization of (THF)3Li(NC)Cu(C6H3-2,6-Mes2) and Br(THF)2Mg (C6H3-2,6-Trip2) (Mes = C6H2-2,4,6-Me3; Trip = C6H2-2,4,6-i-Pr3): The Structures of a Monomeric Lower-Order Lithium Organocyanocuprate and a Bulky Terphenyl Grignard Reagent in
Cheong-Soo Hwang, Philip P. Power
Keywords: Cyanocuprate, Organocopper, Grignard reagent, Terphenyl ligand
DOI: https://doi.org/10.5012/bkcs.2003.24.5.605

Abstract | Full Text: PDF


610  

Thermal Decomposition of Octanethiolate Self-Assembled Monolayers on Cu(111) in UHV
Myung M. Sung, Won J. Yun, Sun S. Lee, Yunsoo Kim
Keywords: Self-assembled monolayers, Octanethiol, Cu(111), Thermal decomposition
DOI: https://doi.org/10.5012/bkcs.2003.24.5.610

Abstract | Full Text: PDF


613  

Hydrothermal Synthesis of Mesostructured Vanadium Oxide and Application of UV-Ozone Treatment
JuYeon Chang, Duk-Young Jung
Keywords: Mesoporous, Vanadium oxide, Hydrothermal
DOI: https://doi.org/10.5012/bkcs.2003.24.5.613

Abstract | Full Text: PDF


617  

Chirospecific Synthesis of D-erythro- and L-threo-Sphinganines from Sugars
Ill-Yun Jeong, Jin Hwan Lee, Byong Won Lee, Jin Hyo Kim, Ki Hun Park
Keywords: D-erythro-Sphinganine, L-threo-Sphinganine, Simultaneous dealkoxyhalogenation, L-Glucono-1,5-lactone, L-Gulonic acid g-lactone
DOI: https://doi.org/10.5012/bkcs.2003.24.5.617

Abstract | Full Text: PDF


623  

Isolation and Synthesis of Tryptamine Derivatives from a Symbiotic Bacterium Xenorhabdus nematophilus PC
Seunguk Paik, Myung Kwang Park, Seong Hoon Jhun, Heai Ku Park, Chun Soo Lee, Bum Rae Cho, Hong Sik Byun, Seok Burm Choe, Seong Il Suh
Keywords: Xenorhabdus nematophilus, Staphylococcus aureus, Nematophin, Tryptamine, L-Isoleucine
DOI: https://doi.org/10.5012/bkcs.2003.24.5.623

Abstract | Full Text: PDF


627  

The pH Studies of Recombinant Acetohydroxy Acid Synthase from Tobacco
Jung-Do Choi, Bok-Hwan Kim, Moon-Young Yoon
Keywords: Acetohydroxy acid synthase, pH study, Tobacco
DOI: https://doi.org/10.5012/bkcs.2003.24.5.627

Abstract | Full Text: PDF


633  

Surface-enhanced Raman Spectroscopy of Quinomethionate Adsorbed on Silver Colloids
Mak Soon Kim, Jae Soo Kang, Si Bum Park, Mu Sang Lee
Keywords: Surface-enhanced Raman spectroscopy, Insectcide, Quinomethionate
DOI: https://doi.org/10.5012/bkcs.2003.24.5.633

Abstract | Full Text: PDF


638  

Chemoselective N-Nitrosation of Secondary Amines under Mild and Heterogeneous Conditions
Mohammad Ali Zolfigol, Arash Ghorbani Choghamarani, Abolfazl Taqian-Nasab, Hassan Keypour, Sadegh Salehzadeh
Keywords: N-Nitosation, Secondary amines, Heterogeneous conditions, N-Nitroso amines
DOI: https://doi.org/10.5012/bkcs.2003.24.5.638

Abstract | Full Text: PDF


641  

Reactivity of [Cp*Rh( h2-NO3)(CF3SO3)] toward Organic Thiols and Cyanate: Preparation and Structures of [Cp*Rh( m-R)3Cp*Rh](CF3SO3) (R = Ph, i-Bu, or Allyl) and [Cp*Rh( h1-NO3)( m-NCO)]2
Won Seok Han, Soon W. Lee
Keywords: Thiols, Cyanate, Dinuclear rhodium, Labile nitrato, Labile triflate
DOI: https://doi.org/10.5012/bkcs.2003.24.5.641

Abstract | Full Text: PDF


645  

Preparation of Phase-Pure InSe Thin Films by MOCVD Using a New Single-Source Precursor [(Me)2In( m-SeMe)]2
Jung Young Cho, Han-Cheol Jeong, Kyung-Soo Kim, Dong Hee Kang, Hong-Ki Kim, Il-Wun Shim
Keywords: Phase-pure InSe thin film, MOCVD, Organometallic precursor
DOI: https://doi.org/10.5012/bkcs.2003.24.5.645

Abstract | Full Text: PDF


647  

Preparation of Copper(Cu) Thin Films by MOCVD and Their Conversion to Copper Selenide (CuSe) Thin Films through Selenium Vapor Deposition
JKyung Soo Kim, Han-Cheol Jeong, Jung Young Cho, Dong Hee Kang, Hong Ki Kim, Hee Min Yoo, Il-Wun Shim
Keywords: Copper thin film by MOCVD, Copper selenide thin film by selenium vapor deposition
DOI: https://doi.org/10.5012/bkcs.2003.24.5.647

Abstract | Full Text: PDF


650  

The Variation of Structure and Transporting Property in SrRu1-xFexO3
Jung-Chul Park, Don Kim, Choong-Sub Lee, Song-Ho Byeon
Keywords: Fe-substituted SrRuO3, Bond-lengths and bond angles, Resistance
DOI: https://doi.org/10.5012/bkcs.2003.24.5.650

Abstract | Full Text: PDF


653  

Reduction of Nitro Group Using Indium-wire in Water
Yong Seo Cho, Bo Kyung Jun, Sanghee Kim, Joo Hwan Cha, Ae Nim Pae, Hun Yeong Koh, Moon Ho Chang, So-Yeop Han
Keywords: Nitro, Reduction, Indium-wire, Water
DOI: https://doi.org/10.5012/bkcs.2003.24.5.653

Abstract | Full Text: PDF


655  

The First Example of Cation Radical Induced Desulfurization from Disulfides
Bo Kyung Park, Wang Keun Lee
Keywords: Thianthrene cation radical, Disulfide, Desulfurization
DOI: https://doi.org/10.5012/bkcs.2003.24.5.655

Abstract | Full Text: PDF


657  

Electrodeposition of 241Am and 244Cm in Spent Nuclear Fuel Samples for Alpha-Spectrometry
Kihsoo Joe, Chang-Heon Lee, Byung-Chul Song, Young-Shin Jeon, Won-Ho Kim, Jeong-Kee Suh
Keywords: Electrodeposition, Alpha-Spectrometry, 241Am, 244Cm, Spent nuclear fuel
DOI: https://doi.org/10.5012/bkcs.2003.24.5.657

Abstract | Full Text: PDF


661  

Novel Synthesis of Phlorin Derivatives and Their Anion Binding Properties
Seong-Jin Hong, Jae-Won Ka, Dong-Hoon Won, Chang-Hee Lee
Keywords: Phlorins, Oxophlorin, Calix[4]phyrin, Chromogenic sensor
DOI: https://doi.org/10.5012/bkcs.2003.24.5.661

Abstract | Full Text: PDF


664  

Non-Phosphopeptide Inhibitor for Lck SH2 Domain: Solid-Phase Synthesis and Structure Activity Relationship of Rosmarinic Acid Analogs
Sun Hee Kang, See-Hyoung Park, Hyeung Soo Shim, Keun-Hyeung Lee
Keywords: Lck SH2, Non-phosphopeptide, Rosmarinic acid, ELISA, Inhibitor
DOI: https://doi.org/10.5012/bkcs.2003.24.5.664

Abstract | Full Text: PDF


667  

The Fluorescent Polydiacetylene Liposome
Eun-Kyung Ji, Dong June Ahn, Jong-Man Kim
Keywords: Polydiacetylene, Biosensor, Liposome, Color change, Fluorescent monomer
DOI: https://doi.org/10.5012/bkcs.2003.24.5.667

Abstract | Full Text: PDF


671  

Reaction Mechanism for the Hydrolysis of Titanium Alkoxides
Jin-Koo Park, Jung-Jae Myoung, Jin-Burm Kyong, Ho-Kun Kim
Keywords: Associative mechanism, Guggenheim method, Bimolecular reaction, Titanium tetra ethoxide
DOI: https://doi.org/10.5012/bkcs.2003.24.5.671

Abstract | Full Text: PDF


674  

Barium-selective Chromoionophoric Properties of Nitro Derivative of Calix[4]arene-crown Ethers
Ju Hee Kim, Suk-Kyu Chang
Keywords: Calix[4]arene, Nitrophenol, Chromoionophore, Barium-selectivity
DOI: https://doi.org/10.5012/bkcs.2003.24.5.674

Abstract | Full Text: PDF


677  

Synthesis of Novel Quinolinecarboxamide Derivatives with Estrogenic Activity
Soo-Jong Um, Si-Ho Park, Chong-Ho Park, Byung-Ha Chang, Jeong-Hyeok Yoon, Hong-Sig Sin
Keywords: Estrogen, Quinolinecarboxamide derivatives, Virtual screening, Functional group, Estrogen receptor (ER)
DOI: https://doi.org/10.5012/bkcs.2003.24.5.677

Abstract | Full Text: PDF


681  

Synthesis and Anion Binding Properties of the Bridged Urea Derivatives of Calix[4]arene
Yong Shik Yang, Seung Whan Ko, In Hee Song, Byung Ju Ryu, Kye Chun Nam
Keywords: Calix[4]arene, Anion receptor, Bridged urea derivative
DOI: https://doi.org/10.5012/bkcs.2003.24.5.681

Abstract | Full Text: PDF


684  

Separation of Nanoparticles in Different Sizes and Compositions by Capillary Electrophoresis
Won-Mi Hwang, Chang-Youl Lee, Doo Wan Boo, Joong-Gill Choi
Keywords: Gold nanoparticles, Polystyrene nanospheres, Capillary electrophoresis, Nanoparticle separation
DOI: https://doi.org/10.5012/bkcs.2003.24.5.684

Abstract | Full Text: PDF