ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 23, Number 10
BKCSDE 23(10)
October 20, 2002 

1359  

One-Pot Conversion of Nitroarenes into N-Arylamides
Ka Young Lee, Jeong Mi Kim, Jae Nyoung Kim
Keywords: Formanilide, Acetanilide, N-Arylamides, Nitroarenes, Iron
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1359

Abstract | Full Text: PDF

1361  

Facile Synthesis of 5-Arylpent-4-enoates from the Baylis-Hillman Acetates
Yang Jin Im, Jeong Mi Kim, Jae Nyoung Kim
Keywords: 5-Arylpent-4-enoates, Baylis-Hillman acetates, Decarbethoxylation, DMAP
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1361

Abstract | Full Text: PDF

1363  

Synthesis of ortho-Acetamidomandelic Acid Derivatives from Isatins
Yun Mi Chung, Ji Hyeon Gong, Jae Nyoung Kim
Keywords: Acetamidomandelic acids, Isatins, Baylis-Hillman reaction
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1363

Abstract | Full Text: PDF

1365  

Development of Mn(III)(Schiff Base) Complexes for the Catalyst of Olefin Oxygenation to Alcohols in the Presence of NaBH4
Nam Ho Lee, Jong Chul Byun, Jong Seok Baik, Chung-Hun Han, Sung-bin Han
Keywords: Oxygenation, Mn(Schiff base) complex, Olefin Oxidation
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1365

Abstract | Full Text: PDF

1367  

Ytterbium(III) Triflate-Catalyzed One-Pot Mannich-Type Reaction in Ionic Liquid
Sang-gi Lee, Jung Hwan Park
Keywords: Ionic liquid, Lanthanide triflates, Mannich
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1367

Abstract | Full Text: PDF

1369  

The Role of β-Turn in the Folding of Mini-Proinsulins
Seung-Gu Chang, Ki-Doo Choi, Dae-Young Kim, Hee-Taik Kang, Myeong-Cheol Song, Hang-Cheol Shin
Keywords: b-Turn, Folding, Mini-proinsulin
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1369

Abstract | Full Text: PDF

1371  

Mechanism of Cell Growth Inhibition by Menadione
Seung Wook Ham, Soomee Jin, Jeung Hwan Song
Keywords: Menadione, Phosphatase
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1371

Abstract | Full Text: PDF

1373  

Isolation and Identification of Oleamide as a Growth Inhibitory Compound from the Medium Conditioned by Colon Cancer Cells Treated with Conjugated Linoleic Acid
Jung Han, Yoon Park, Eun Ji Kim, Hyunyong Jin, Jong-Gab Jun
Keywords: Conjugated linoleic acid, Caco-2 cells, Colon cancer, Oleamide
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1373

Abstract | Full Text: PDF

1375  

Facile β-Alkylation and β-Hydroxyalkylation of α, β-Unsaturated Lactones and Esters
Sun Ho Jung, Jung Hyun Kim
Keywords: Phosphoniosilylation, b-Alkylation, b-Hydroxyalkylation, a, b-Unsaturated lactones and esters
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1375

Abstract | Full Text: PDF

1377  

Reaction of Epoxides with Boron Triisopropoxide.The Meerwein-Ponndorf-Verley Type Reduction of Boron Alkoxides.21
Jin Soon Cha, Jae Hyung Park
Keywords: Epoxide ring-opening, Reduction, Boron triisopropoxide, MPV type reaction
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1377

Abstract | Full Text: PDF

1379  

Highly Cesium Selective Calix[6]arene Receptors: Synthesis, Structure and Cesium Binding Properties of Calix[6]arene Biscrown
Seung Whan Ko, Yong Shik Yang, Jung Hwa Mun, Ki-Min Park, Shim Sung Lee, Kye Chun Nam
Keywords: Calix[6]arene, Biscrown, Cesium selective receptor
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1379

Abstract | Full Text: PDF

1381  

Extraction Equilibria and Solvent Sublation for Determination of Ultra Trace Bi(III), In(III) and Tl(III) in Water Samples by Ion-Pairs of Metal-2-Naphthoate Complexes and Tetrabutylammonium Ion
Young-Sang Kim, Yoon-seok Choi, Won Lee
Keywords: Solvent sublation, 2-Naphthoic acid, Ion-pair formation, Solvent extraction, Flotation technique
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1381

Abstract | Full Text: PDF

1389  

The Matrix Effect of Biological Concomitant Element on the Signal Intensity of Ge, As, and Se in Inductively Coupled Plasma/Mass Spectrometry
Kyung-Su Park, Sun-Tae Kim, Young-Man Kim, Yunje Kim, Won Lee
Keywords: Matrix effect, Serum, Urine, ICP/MS
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1389

Abstract | Full Text: PDF

1394  

Novel Copper(II)-Selective Sensor Based on a New Hexadentates Schiff’s Base
Mohammad Reza Ganjali, Mehdi Emami, Masoud Salavati-Niasari
Keywords: Copper, Potentiometry, Hexadentates Schiff’s base, Sensor, Electrode
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1394

Abstract | Full Text: PDF

1399  

Development of an Enzyme-Linked Immunosorbent Assay for the Organophosphorus Insecticide Bromophos
Won Chul Park, Young Ae Cho, Yoo Jung Kim, Bruce D. Hammock, Yong Tae Lee, Hye-Sung Lee
Keywords: Bromophos, Insecticide, Immunoassay, ELISA
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1399

Abstract | Full Text: PDF

1404  

Relationships between the Raman Excitation Photon Energies and Its Wavenumbers in Doped trans-Polyacetylene
Jin-Yeol Kim, Eung-Ryul Kim, Dae-Woo Ihm, Mitsuo Tasumi
Keywords: Polyacetylene, Raman spectroscopy
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1404

Abstract | Full Text: PDF

1409  

Polymeric Acetate-Selective Electrodes Based on meso-( α,α,α,α)-Tetrakis-[(2-arylphenylurea)phenyl]porphyrins: Electronic and pH Effects
Hyo Kyoung Lee, Kiju Song, Hyung Ran Seo, Seungwon Jeon
Keywords: Polymeric membrane, Urea-functionalized porphyrin, Acetate ion, Ion-selective electrode, Neutral ionophore
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1409

Abstract | Full Text: PDF

1413  

Hapten Synthesis and Influence of Coating Ligands on Enzyme-linked Immunoreaction of DDT
Ji Youn Hong, Jong-Hyun Kim, Myung Ja Choi
Keywords: Immunoreaction, DDT, Coating ligand, Polyclonal antibody
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1413

Abstract | Full Text: PDF

1420  

Synthesis of Tripodal Trifluoroacetophenone Derivatives and Their Evaluation as Ion-Selective Electrode Membranes
Young Kook Kim, Jeonghan Ha, Geun Sig Cha, Kyo Han Ahn
Keywords: Tripodal ionophores, Trifluoroacetophenone, Carbonate anion, Ion-selective electrode
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1420

Abstract | Full Text: PDF

1425  

Synthesis of 6,7-Dichloro-5,8-phthalazinedione and Its Derivatives
Jin Sung Kim, Kye Jung Shin, Dong Chan Kim, Yong Koo Kang, Dong Jin Kim, Kyung Ho Yoo, Sang Woo Park
Keywords: Phthalazine, Efficient synthetic route, Chloroxidation, 6,7-Dichloro-5,8-phthalazinedione
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1425

Abstract | Full Text: PDF

1429  

Absolute Stereochemistry Determination of Tetrin B
Geonseek Ryu, Byoung Wook Choi, Bong Ho Lee
Keywords: Tetrin B, Absolute stereochemistry
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1429

Abstract | Full Text: PDF

1435  

The Optical Properties of (Y1-xGdx)3-z(Al1-yGay)5O12:Cez Phosphors for White LED
Young-Duk Huh, Young-Shik Cho, Young Rag Do
Keywords: Phosphors, White LED
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1435

Abstract | Full Text: PDF

1439  

Design and Synthesis of Quipazine Based Re-Complexes for the Development of Potential SPECT Imaging Agents with 99m Tc for 5-HT Transporter
Mi-Young In, Dae Yoon Chi, Sun-Ju Choi, Kyung-Bae Park, Cheon-Gyu Cho
Keywords: Serotonin, Radiotracer, SPECT, Technetium, Rhenium
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1439

Abstract | Full Text: PDF

1445  

Correlation of the Rates of Solvolysis of Phenyl Chlorodithioformate
Sun Kyoung An, Jin Soon Yang, Jun Mi Cho, Kiyull Yang, Jong Pal Lee, T. W. Bentley, Ikchoon Lee, In Sun Koo
Keywords: Chlorodithioformate, Ionizing power, Nucleophilicity, Solvolysis
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1445

Abstract | Full Text: PDF

1451  

Activation of Phospholipase D in Rat Thymocytes by Sphingosine
Youngkyun Lee, Myung-Un Choi
Keywords: Sphingosine, Phospholipase D, Calcium, Thymocytes
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1451

Abstract | Full Text: PDF

1456  

Spectrofluorimetric Determination of Oxalate Based on Its Ternary Complex between Eu 3+ and Thenoyltrifluoroacetone
Ki Won Cha, Hua Zi Huang, Hyun Cheol Choi
Keywords: Oxalate, Eu3+, Thenoyltrifluoroacetone (TTA), Fluorescence, Enhancement
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1456

Abstract | Full Text: PDF

1459  

Kinetic Studies on the Nucleophilic Addition Reactions of Vinylic β-Diketones
Hyuck Keun Oh, Jae Myon Lee
Keywords: Nucleophilic addition reaction, Single-step process, Cross-interaction constant, Kinetic isotope effect, Four-center cyclic transition state
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1459

Abstract | Full Text: PDF

1463  

Ferroelectric Properties of Substituted Aurivillius Phases SrBi2Nb2-xMxO9 (M=Cr, Mo)
S.-Y. Moon, K. S. Choi, K. W. Jung, H. Lee, D. Jung
Keywords: Aurivillius phase, Ferroelectric property, Dielectric constant
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1463

Abstract | Full Text: PDF

1467  

Cyclitol Derivatives from the Sponge Sarcotragus Species
Yonghong Liu, Chong O. Lee, Jongki Hong, Jee H. Jung
Keywords: Cyclitol, Marine sponge, Sarcotragus, Cytotoxicity
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1467

Abstract | Full Text: PDF

1470  

Luminescence Properties of Poly[2-(4’-t-butylphenoxy)-1,4-phenylenevinylene]
Nguyen Phuong Hoai Nam, Veena Prasad, Soon Wook Cha, Dong Won Lee, Jung-Il Jin
Keywords: PPV derivative, Electroluminescence, Photoluminescence, Polymer LED
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1470

Abstract | Full Text: PDF

1473  

Identification of 6-Deoxocastasterone and Brassinolide from a Liverwort,Marchantia polymorpha
Young-Soo Kim, Soon Young Kim, Seong-Ki Kim, Jae Kuk Shim
Keywords: Brassinosteroids, Biosynthesis, The late C6-Oxidation pathway, Liverwort, Marchantia polymorpha
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1473

Abstract | Full Text: PDF

1477  

Ceric Ammonium Nitrate(CAN)-Mediated Oxidative Cycloaddition of 1,3-Dicarbonyls to Vinyl Sulfides.Application to the Synthesis of Evodone and Avicequinone-B
Yong Rok Lee, Gun Joon Lee, Keon Yong Kang
Keywords: Ceric ammonium nitrate, 1,3-Dicarbonyls, Vinyl sulfides, Evodone, Avicequinone-B
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1477

Abstract | Full Text: PDF

1481  

Facile Synthesis of 5-Carboxylate Substituted Piperazin-2-ones as Peptidomimetic Agents
Yong Jun Chung, Youn-Chul Kim, Ho-Jin Park
Keywords: Peptidomimetic, Anti-angiogenic, Piperazin-2-one, Tandem reaction
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1481

Abstract | Full Text: PDF

1483  

Peptide-Binding Macrocycles Based on Trimesic Acid and 1,2-Diamines
Ji Eun Jung, Seung Soo Yoon
Keywords: Molecular recognition, Peptide-Binding
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1483

Abstract | Full Text: PDF

1487  

Chiral Phosphinooxazolidine Ligand Derived from Prolinol:Application to the Pd-Catalyzed Asymmetric Allylic Alkylation
Myung-Jong Jin, Sang-Joon Lee, Young-Mok Kim
Keywords: Asymmetric catalysis, Allylic alkylation, Phosphinooxazolidine, Pd complex
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1487

Abstract | Full Text: PDF

1490  

Enzymatic Introduction of Cyanide into Imine for Constructing Optically Active Compound by (R)-Oxy-nitrilase in Almond Meal
Teckheon Lee, Yonghyun Ahn
Keywords: Cyanide, Imine, Oxynitrilase, Hydroxynitrile lyase
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1490

Abstract | Full Text: PDF

1493  

Facile Synthesis of 3-Alkoxymethyl 2(1H)-Quinolinones from the Baylis-Hillman Adducts of 2-Nitrobenzaldehydes
Ka Young Lee, Jeong Mi Kim, Jae Nyoung Kim
Keywords: 2(1H)-Quinolinone, Baylis-Hillman adducts, 2-Nitrobenzaldehydes, Tin(II) chloride.
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1493

Abstract | Full Text: PDF

1496  

Rapid Monitoring Method of Active and Passive Smoker with Saliva Cotinine by Gas Chromatography-Mass Spectrometry
Jin-gu Kim, Ueon-Sang Shin, Ho-Sang Shin
Keywords: ETS monitoring, Cotinine, Saliva, GC-MS
DOI: https://doi.org/10.5012/bkcs.2002.23.10.1496

Abstract | Full Text: PDF