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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 41, Number 9
JKCSEZ 41(9)
June 20, 1997

Title	The Effect of Pressure on the Rate of Solvolysis (Ⅲ) Kinetics on the Nucleophilic Substitution Reactions of Acyl- and Alkyl Groups in Binary Solvents 가용매분해반응속도에 대한 압력의 영향(III) 이성분용매내 Acyl류와 Alkyl류의 친핵성 치환반응의 속도론적 연구
Author	Jin-Burm Kyong, Byoung-Chun Park, Oh-Cheun Kwun 경진범, 박병춘, 권오천
Keywords
Abstract	여러가지 수용성 혼합용매내에서 파라 치환체인 acylchloride류와 alkyl chloride류의 가용매분해 반응속도를 여러 온도와 압력하에서 전도도 방법에 의하여 측정하였다. 이들 속도상수로 부터 활성화 파라미터들(△V≠, 俎≠, △S≠)을 구하였다. 또한 활성화 부피와 활성화 엔트로피 관계로 부터 이들 반응에 대한 반응성을 조사하였다. Kinetics for the solvolyses of acyl chlorides and alkyl chlorides in hydroxylic solvent mixtures have been measured by conductometric method at various temperatures and pressures. The activation parameters (ΔV≠, ΔH≠, ΔS≠) were estimated from the rate constants. The reactivities of these reactions were also estimated from the correlation of the activation volumes with the activation entropies.
Page	443 - 448
Full Text	PDF

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