ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 38, Number 8
JKCSEZ 38(8)
April 20, 1994 

Light-induced electron transfer reaction within binuclear complex (NC)5FeⅡ-L-CoⅢ(NH3)5 was studied with steady-state photolysis and the rate constants were measured for various bridging lignands. klight and quantum yields for BP, PHEN, DAP having conjugation between metal binding sites were about 3×10-2 sec-1 and 1, and for BPEA having no conjugation were about 2×10-4 sec-1 and 0.03. Light-induced electron transfer reaction within binuclear complex was proved to be the chemical mechanism which had charge transfer excited state MLCT*.