ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 37, Number 12
JKCSEZ 37(12)
December 20, 1993 

A series of New N-[1-(benzotriazol-1-yl)-X-substituted benzyl]-Y-substituted aniline derivaties (S) have been synthesized. And the rate of hydrolysis was investigated kinetically in 25% (v/v) aqueous methanol at 25℃. On the basis of rate equations, solvent effect m ≪ 1, n ≤ 3 and m ≪ l), salt effect, general base catalysis, substituent effect (ρxy > 0), and hydrolysis products analysis, it may be concluded that the hydrolysis of N-[1-(benzotriazol-1-yl)benzyl]aniline proceeds the "A-SN2" mechanism below pH 12.0, while above pH 13.0, the hydrolysis proceeds through a typical "SN2" mechanism.