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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 37, Number 7
JKCSEZ 37(7)
February 20, 1993 

Metal Complexes of Ambidentate Ligand (Ⅷ). Ni (Ⅱ) and Pd (Ⅱ) Complexes of Isonitrosomethylacetoacetate Imines

Ambidentate 리간드의 금속착물 (제 8 보). Isonitrosomethylacetoacetate Imine 리간드의 니켈(Ⅱ) 및 팔라듐(Ⅱ) 착물
Bon-Chang Goo, Gang-Yeol Choi, Man-Ho Lee, In-Whan Kim

구본창, 최강렬, 이만호, 김인환
isonitrosomethylacetoacetate(H-IMAA)의 이민유도체를 리간드로하는 새로운 Ni(Ⅱ) 및 Pd(Ⅱ)착물, Ni(IMAA-NH)(IMAA-NH'), Ni(IMAA-NH)(IMAA-NR), Pd(IMAA-NH)2, 및 Pd(IMAA-NR)2(R = CH3, C2H5, n-C3H7, n-C4H9, 또는 CH2C6H5)을 합성하고, 이들 착물의 구조를 원소분석, 전자흡수분광법, 적외선흡수분광법, 1H 및 13C 핵자기공명분광법으로 조사하였다. 여기서 H-IMAA-MH 및 H-IMAA-NR은 각각 isonitrosomethylacetoacetate imine 및 N-alkylisonitrosomethylacetoacetate imine 유도체를 나타낸다.

New Ni(Ⅱ) and Pd(Ⅱ) complexes of isonitrosomethylacetoacetate imine derivatives, Ni(IMAA-NH)(IMAA-NH'), Ni(IMAA-NH)(IMAA-NR), Pd(IMAA-NH)2 and Pd(IMAA-NR)2 (R = CH3, C2H5, n-C3H7, n-C4H9, or CH2C6H5), where H-IMAA-NH and H-IMAA-NR represent isonitrosomethylacetoacetate imine and N-alkylisonitrosomethylacetoacetate imine derivative, respectively, have been prepared and the structures of the complexes have been studied by elemental analyses, electronic, infrared, and 1H- and 13C-NMR spectroscopies.

662 - 671
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