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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 37, Number 6
JKCSEZ 37(6)
December 20, 1993 

 
Title
Studies on the Photo-Electrochemical Properties of TiO2-x Thin Films Prepared by Air Oxidation and Water Vapor Oxidation

공기 산화와 수증기 산화에 의해 제조된 TiO2-x박막의 광전기화학적 성질에 관한 연구
Author
Yong-Kook Choi, Ki-Hyung Chjo, Q-Won Choi, Jeong-Geun Oh, Jeong-Sub Seong

최용국, 조기형, 최규원, 오정근, 성정섭
Keywords
Abstract
티타늄 금속판을 공기산화와 수증기 산화하여 만든 TiO2-x 박막을 시료로 사용하여 1M NaOH 용액에서 광전기화학적 성질을 연구하였다. 높은 온도에서 제조된 TiO2-x 전극들은 낮은 온도에서 제조된 전극들보다 더 음의 값으로 주어지는 flat band potential(Vfb)과 더 높은 donor density(ND)를 가졌다. 전극전위의 변화에 따른 광전류 측정과 Mott-Schottky plot로부터 얻은 Vfb는 -0.95 ∼ -1.1 V 사이에서 비슷한 값으로 주어졌다. 자외부 영역의 광을 완전히 차단하는 TiO2 단결정을 필터로 하여 가시부 영역의 광전류를 측정할 때 분해능이 좋은 slit를 사용한 경우 좋은 sub band gap 광반응을 볼 수 있었다.

The titanium oxide thin film was prepared by air oxidation and water vapor oxidation. The photo-electrochemical properties of the electrode was studied in 1M NaOH solution. Titanium dioxide electrodes prepared at higher temperatures were found to have slightly more negative flat band potentials and slightly higher donor densities than their low temperature counterparts. The value of flat band potential (Vfb) was obtained to be -0.95 ∼ -1.1 V by the measurement of photocurrent and Motte-Schottky plots. The photocurrent of visible region was measured in terms of single crystal filter which entirely blocks the UV radiation. The photo-response of electrodes appeared good with the measument by direct current, when the slit of great resolution was used.

Page
549 - 554
Full Text
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