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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 37, Number 2
JKCSEZ 37(2)
April 20, 1993

Title	Metal Complexes of Sulfur-containing Ligands Ⅰ. Syntheses and Properties of Nickel(Ⅱ) Complexes of Dithiocarbamates 황함유리간드의 금속착물 Ⅰ. 디티오카바메이트류의 니켈(Ⅱ)착물의 합성과 그 성질
Author	In-Sik Kim, Chan-Woo Kim, Chang-Su Kim 김인식, 김찬우, 김창수
Keywords
Abstract	즈비터이온인 디티오카바메이트류의 암모늄과 이를 리간드로 한 니켈(Ⅱ)착물을 합성하였다. 이들 니켈(Ⅱ)착물의 적외선 및 전자흡수 스펙트럼과 전도도, 질량분석 등으로 그 특성을 조사하였다. 이들 니켈(Ⅱ)의 디티오카바마토류 착물은 물, 메탄올 및 아세톤과 같은 극성용매에 녹는다. 이들 니켈(Ⅱ)착물의 원소분석과 물리적 측정 결과에서부터 그 가능한 구조를 제시하였다. Syntheses and properties of zwitterionic dithiocarbamates and their nickel(Ⅱ) complexes are described. The complexes have been characterized by mass infrared and electronic absorption spectroscopy, and conductivity measurement. Ni(Ⅱ)-dithiocarbamato complexes are soluble in polar solvents such as water, methanol, and acetone etc. The possible structures were proposed on the basis of elemental analyses and physical properties.
Page	206 - 212
Full Text	PDF

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