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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 35, Number 1
JKCSEZ 35(1)
February 20, 1991 

Halogenation of Cannabinoids

Cannabinoid의 할로겐화
Seung-Hwa Baek, No-Yeun Park

백승화, 박노윤
카나비노이드의 할로겐화 반응은 metal halide와 함께 18-crown-6 존재하에 m-chloroperbenzoic acid에 의해 좋은 수득률의 산화반응이 일어났다. 이 반응계에서는 할로겐화 반응이 방향족 고리에만 선택적으로 일어났다.

Several types of cannabinoids have been halogenated in the aromatic ring in good yields with metal halide in the presence of 18-crown-6 on oxidation with m-chloroperbenzoic acid. This reagent system effects the regiospecific halogenation of activated aromatic ring over olefinic double bond.

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