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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 34, Number 6
JKCSEZ 34(6)
December 20, 1990 

The Synthesis of Pyrimidine Derivatives Containing H-Chelate

H-킬레이트가 있는 피리미딘 유도체들의 합성
Jung Hwan Kim, Jeong Hyeob Seo

김정환, 서정협
분자내에서의 전자에너지 전달시스템의 골격으로서 Bis (4,6-dichloropyrimidine-5-yl) alkanes류를 합성하였으며, 이화합물과 2-cyanomethylquinoline을 반응시켜 α-(4-cyanomethylquinoline-6-chloropyrimidine-5-yl)-ω-(4,6-dichloropyrimidine-5-yl) alkanes의 H-chelate를 합성하였다. 이들 화합물에 대한 구조는 분광학적인 방법으로 연구하였다.

Bis (4,6-dichloropyrimidine-5-yl) alkanes as the frame of "intramolecular electronic energy transfer" system have been synthesized and the H-chelates of α-(4-cyanomethylquinoline-6-chloropyrimidine-5-yl)-ω-(4,6-dichloropyrimidine-5-yl) alkanes have been synthesized from bis (4,6-dichloropyrimidine-5-yl) alkanes and 2-cyanomethylquinoline. The structures of the compounds have been studied by spectral methods.

637 - 640
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