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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 34, Number 6
JKCSEZ 34(6)
December 20, 1990

Title	A Study for Oxidation Reaction of Alcohols with Cr (Ⅵ)-Isoquinoline Compound (Ⅰ) Cr (Ⅵ)-Isoquinoline 화합물에 의한 알코올들의 산화반응에 관한 연구 (Ⅰ)
Author	Jung Sung Yang, Young Cho Park, Hyung Chul Baek 양정성, 박영조 ,백형철
Keywords
Abstract	H2O을 용매로 하여 헤테로고리 염기인 이소퀴놀린과 CrO3를 반응시켜 Cr(Ⅵ)화합물인 [C9H7NH]2Cr2O7을 얻었다. 이 화합물은 비흡수성이면서 물에 잘 녹았다. 그리고 원소분석, 적외선 분광법으로 이 화합물의 구조가 [C9H7NH]2Cr2O7임을 확인하였다. 또한, 이 화합물이 여러 가지 알코올을 알데히드나 케톤으로 전환시킬 수 있는 산화제로 작용하는가를 알아보기 위하여 알릴, 일차, 이차 알코올을 각각 산화반응에 이용한 결과 알코올들에 대해 효율적인 산화제로 작용하였다. Chromium(Ⅵ) compound, [C9H7NH]2Cr2O7 has been prepared by the reaction of isoquinoline with chromium trioxide under the presence of water. [C9H7NH]2Cr2O7 is nonhydroscopic and dissolved in water very well. Structure of [C9H7NH]2Cr2O7 is identified by FTIR spectra and elemental analysis data. The ability of [C9H7NH]2Cr2O7 for the oxidation of alcohols were examined in methylene chloride. [C9H7NH]2Cr2O7 was found as efficient oxidizing agent for the conversion of allyl, primary and secondary alcohols to the corresponding aldehydes or ketones.
Page	534 - 538
Full Text	PDF

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