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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 34, Number 5
JKCSEZ 34(5)
October 20, 1990 

 
Title
Synthesis and Characterization of Molybdenum (0) Complexes with Various Alkadienes

몰리브덴늄 (0)-알카디엔화합물의 합성 및 확인
Author
Sock Sung Yun, Yun Dong Choi, In Soon Chang

윤석승, 최윤동, 장인순
Keywords
Abstract
금속원자 반응기를 사용하여 몰리브덴 금속증기와 1,3-butadiene 유도체를 반응시켜서 (η4-CH2CRCR'CH2)3Mo(R, R'= H 또는 CH3)를 합성하였으며, 이 때 생성된 유기금속화합물에 대한 1,3-butadiene 유도체의 메틸치환기 효과에 대하여 논의하였다. 그리고 몰리브덴 금속증기와 다른 몇 가지 알카디엔화합물을 반응시켜서 유기금속화합물이 형성됨을 확인하였으며 이들은 공기 중의 실온에서 쉽게 분해 되었다. 또한 (η4-CH2CCH3CCH3CH2)3Mo와 일산화탄소를 반응시켜서 (C6H10)2(CO)3Mo를 합성하였으며 이 화합물의 금속-리간드 결합에 관하여 논하였다.

Various tris (η4-diene) molybdenums were easily synthesized by the reaction of various 1,3-dienes and molybdenum metal vapors by using metal atom reactor. The methyl substituent effect of the tris (η4-diene) molybdenum produced were discussed. And some alkadiene-molybdenum complexes which were easily decomposed in the air at room temperature were also formed.(C6H10)2(CO)3Mo were synthesized and its molybdenum-diene bond type were discussed.

Page
430 - 437
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