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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 33, Number 2
JKCSEZ 33(2)
April 20, 1989 

 
Title
pH Measurement Using Isosbestic Point of Indicator

지시약의 등흡광점을 이용한 용액의 pH 측정
Author
Won-Hyung Choi, Ho-Jang Hur

최원형, 허호장
Keywords
Abstract
지시약 메틸레드 용액을 시료용액에 첨가하고 지시약의 산형의 최대흡수파장과 염기형의 최대 흡수파장 및 등흡광점에서 이 시료액 흡광도를 측정하였다. 이를 측정한 흡광도로부터 이 용액의 pH를 계산하였다. 등흡광점에서 흡광도 범위를 0.1내지 0.3으로 유지하고 시료용액의 pH가 pKpK±1내에서, pH측정오차는 ±0.08pH 단위 이내이었다.

The methyl red stock solution was added to sample solution and the absorbance values of this solution were measured at the maximum absorption wavelengths of the acidic form, the basic form, and the isosbestic point of the indicator. From the measurements of absorbance, the pH of this solution was calculated. The range of absorbance at the isosbestic point was maintained within 0.1 ∼ 0.3. The error of pH measurement was within ±0.08 pH unit in the pH range of sample solution of pK±1.

Page
203 - 207
Full Text
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