KCS Publications

HOME > Search > Browsing(JKCS) > Archives

Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 31, Number 5
JKCSEZ 31(5)
October 20, 1987

Title	Studies on the Synthesis and Structure of Macrocyclic Complexes for Transition Metals. (Part 1) Effects of Stability Constant on the Co-formation of Mixed Chelates (EDTA and IMDA) with Lanthanon (La, Nd, Gd, Ho, Yb) 전이금속 착물들의 합성 및 결정구조 연구 (제 1 보) EDTA 와 IMDA 복합 킬레이트가 란탄족 원소들 (La, Nd, Gd, Ho, Yb)의 안정도 상수에 미치는 영향
Author	Young-Gu Ha, E. Y. Kim, Q. Won Choi, Hasuck Kim 하영구, 김은연, 최규원, 김하석
Keywords
Abstract	Ln-EDTA 1 : 1 착물과 IMDA 사이의 착물형성에 대한 안정도 상수들을 이온세기 μ = 0.1, KNO3와 20.0±0.2℃에서 전위차 적정법으로 연구하였다. Ln(EDTA)(IMDA) 혼합리간드착물들에 비교적 큰 안정도 상수가 형성된다는 사실을 밝혔으며, Ln원소들의 원자번호에 대한 형성도상수들의 경향을 Ln원소의 배위수와 반지름의 바탕에서 고찰하였다. The formation constants of the complexes between Ln-EDTA 1 : 1 complex and IMDA have been investigated by a potentiometric titration method at 20.0±0.2 degree C and μ = 0.1 (KNO3). Unusually large stability in Ln(EDTA) mixed ligand complexes was found. Trends in the formation constants vs. atomic number of the lanthanide metals were discussed on the basis of coordination number and ionic radius of the metals.
Page	434 - 443
Full Text	PDF

How to access to the WOL for The Bulletin of the Korean Chemical Society ?

The Bulletin of the Korean Chemical Society will be co-published with Wiley-VCH from 2015 towards. The online version of the Journal will thus be available on Wiley Online Library, Wiley(-VCH)'s global online platform.

KCS members can get a free online access to the Bulletin of the Korean Chemical Society in WOL.

Free Access to WOL