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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 31, Number 4
JKCSEZ 31(4)
August 20, 1987 

Synthesis of Nucleophilic Adducts of thiols (Ⅷ). Addition of Thioglycolic acid, Benzenethiol and Benzylmercaptan to β-Acetyl-β-benzoylstyrene Derivatives
Tae-Sung Huh, In-Sook Baek, Kih-Lim Seo, Tae-Rim Kim
β-acetyl-β-benzoylstyrene 유도체에 대한 thioglycolic acid, benzenethiol, 및 benzylmercaptan의 첨가반응에 관하여 연구하였다. β-acetyl-β-benzoylstyrene 유도체는 쉽게 thioglycolic acid, benzenethiol, and benzylmercaptan과 반응하여 다섯가지 (2-acetyl-2-benzoyl-1-phenylethyl)thioglycolic acid 유도체 (Ⅱa-Ⅱe), 다섯가지의 (2-acetyl-2-benzoyl-1-phenylethyl)benzenethiol 유도체(Ⅲa-Ⅲe) 및 다섯가지의 (2-acetyl-2-benzoyl-1-phenylethyl)benzylmercaptan 유도체 (Ⅳa-Ⅳe)를 합성한다.

The addition reactions of thioglycolic acid, benzenethiol and benzylmercaptan to β-acetyl-β-benzoylstyrene were investigated. β-Acetyl-β-benzoylstyrene derivatives easily underwent addition reactions with thioglycolic acid, benzenethiol, and benzylmercaptan to form five (2-acetyl-2-benzoyl-1-phenylethyl)thioglycolic acid derivatives (Ⅱa-Ⅱe), five (2-acetyl-2-benzoyl-1-phenylethyl)benzenethiol (Ⅲa-Ⅲe) derivatives and five (2-acetyl-2-benzoyl-1-phenylethyl)benzylmercaptan derivatives (Ⅳa-Ⅳe), respectively.

364 - 368
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