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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 30, Number 6
JKCSEZ 30(6)
December 20, 1986 

A Study on Solid Electrolyte for New Type Cell

고체 전해질을 이용한 새로운 전지에 관한 연구
Sung Ho Park, Seung Gu Cho, Keu Hong Kim, Young Bae Kim, Jae Shi Choi

박성호, 조승구, 김규홍, 김용배, 최재시
새로운 전지의 개발을 위하여 AgI-Ag8S3SO4system들을 만들어 이에 대한 전기전도도 측정, 상 연구 및 그 구조를 조사하였다. X-ray powder diffraction method로 20mole% Ag8S3SO4-AgI system의 구조가 단사정계임을 규명하였고 DTA method로 단일상을 이룸을 확인하였다. 4-probe method를 적용시켜 전기전도도를 측정한 결과 20mole% Ag8S3SO4-AgI system이 순수한 Ag+ 이온성 couduct임을 밝힐 수가 있었다.

For the development of new type cell, a study on new electrolyte, AgI-Ag8S3SO4 system has been carried out by using electrical conductivity measurement, DTA and X-ray powder diffraction method. From both X-ray powder diffraction and DTA method, it is clearly known that 20mole% Ag8S3SO4-AgI system forms single phase, having monoclinic structure. It is also found that 20mole% Ag8S3SO4-AgI system is purely Ag+ cation conduction from results of conductivity measurement by applying 4-probe method.

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