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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 30, Number 5
JKCSEZ 30(5)
October 20, 1986 
 
Title
 Rates and Mechanism of Reduction of Vanadium(V) by Ethanol in Sulfuric Acid

황산용액에서 에탄올에 의한 바나듐(Ⅴ) 의 환원반응의 속도와 메카니즘
Author
 Chang-Su Kim, Woo-Sik Lee

김창수, 이우식
Keywords
Abstract
 황산용액에서 에탄올에 의한 VO2+이온을 환원시키면 황산바나딜(Ⅳ)가 생성된다. 생성물 VOSO4를 포함하는 용액에 대한 분광학적 결과가 보고된다. 에탄올에 의한 VO2+의 환원에 대한 속도론적 연구는 35℃와 50℃에서 행하여 졌다. VO2+의 환원반응메카니즘이 논의되었다.

The reduction of VO2+ ion by ethanol in sulfuric acid leads to the formation of vanadyl sulfate. Spectrophotometric measurements on the solution containing products, vanadyl sulfate, are also reported. Kinetic studies on reduction of VO2+ by ethanol have been carried out at 35℃ and 50℃. The reaction mechanism for reduction of VO2+ is discussed.
Page
 409 - 414
Full Text
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