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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 28, Number 6
JKCSEZ 28(6)
December 20, 1984 

 
Title
Reaction of 2-Mercaptobenzothiazole

2-Mercaptobenzothiazole의 반응
Author
In Kyu Kim, Sun Il Kim, Chan Mo Yu, Il-Gook Chung, Joon Won Park, Sang Chul Shim

김인규, 김순일, 유찬모, 정일국, 박준원 ,심상철
Keywords
Abstract
2-Mercaptobenzothiazole과 알코올로부터 여러가지 알킬유도체를 얻을 수 있었다. 이 방법은 알려진 다른 방법보다 간편하고 수율도 좋고 또 일반성이 있는 장점이 있다. 이렇게 해서 얻은 2-mercaptobenzothiazole에 염소화 반응을 시도한 결과 2-chloromethylthiobenzothiazole을 얻을 수 있었다.

A highly efficient and general route to obtain the alkyl derivatives of 2-mercaptobenzothiazole is described. Depending on the reaction conditions 2-methylmercaptobenzothiazole gave various products with chlorinating agents probably due to the lability of the probable chlorosulfonium ion intermediate.

Page
412 - 417
Full Text
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