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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 28, Number 6
JKCSEZ 28(6)
December 20, 1984

Title	Dichloro Platinum (Ⅱ) Complex of S-6,6'-Dimethyl-2,2'-diaminobiphenyl S-6,6'-Dimethyl-2,2'-diaminobiphenyl 리간드의 디클로로백금 (Ⅱ) 착물
Author	Moo-Jin Jun, Sung-Rack Choi 전무진, 최승락
Keywords
Abstract	l-tartaric acid를 이용하여 두자리 아민리간드인 6,6'-dimethyl-2,2'-dia minobiphenyl (dmdabp)를 분할하여 S광학이성질체인 S-dmdabp를 얻었다. S-dmdabp로 부터 평면사각형 착물[Pt(S-dmdabp)Cl2]를 합성하였으며, 이 착물에서 S-dmdabp 리간드가 δ-confomation으로 배위 되어 있음을 확인하였다. The S-enantiomer of the 6,6'-dimethyl-2,2'-dia minobiphenyl (dmdabp) has been obtained by resolving dmdabp with l-tartaric acid. The square planar dichloro platinum(Ⅱ) complex has been prepared with the optically active S-dmdabp, which is found to take the conformation in the [Pt(S-dmdabp)Cl2] complex.
Page	399 - 402
Full Text	PDF

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