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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 28, Number 6
JKCSEZ 28(6)
December 20, 1984

Title	Vibration-Vibration Energy Transfer between H79Br and H81Br H79Br과 H81Br간의 진동 → 진동에너지 이동
Author	Chang Soon Lee, Yoo Hang Kim, Hyung Kyu Shin 이창순, 김유항, 신형규
Keywords
Abstract	공명 진동→진동 에너지 이동 과정, H79Br(v = 1) ＋ H81Br(v = 0) → H79Br(v = 0) ＋ H81Br(v = 1) ＋ ΔE = 0.38 cm-1에 대해 long-lived 충돌모형을 적용하여 에너지 이동 확률을 200 - 800K 범위에서 계산하였다. 계산된 확률은 온도가 상승함에 따라 감소하며 온도 의존성은 P ∝ T -1.8이었다. 또한 계산된 확률은 다른 이론들로부터 계산한 확률들 보다 알려져 있는 실험치와 더 잘 일치하였다. The long-lived collision model has been applied to the resonant vibration-vibration energy exchange process H79Br(v = 1) ＋ H81Br(v = 0) → H79Br(v = 0) ＋ H81Br(v = 1) ＋ ΔE = 0.38 cm-1. The energy exchange probabilities have been calculated over the temperature range from 200 to 800K. They show negative temperature dependence (P ∝ T -1.8) and agree with the available experimental data better than those calculated from other theories.
Page	361 - 365
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