ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 27, Number 2
JKCSEZ 27(2)
April 20, 1983 

13C and 51V NMR spectroscopy have been used to study the solution structures of the vanadium (Ⅴ) complexes formed by ethylenediaminetetraacetic acid (EDTA), trans-cyclohexanediaminetetraacetic acid (CDTA), 1,2-propylenediaminetetraacetic acid (PDTA), ethylenediaminediacetic acid (EDDA), 2-hydroxyethylethylenediaminetriacetic acid (HEDTA), diethylenetriaminepentacetic acid (DPTA), and nitrilotriacetic acid (NTA). All of the complexes probably have octahedral structures containiing cis-VO2 core. The coordination of hydroxylethyl group is found to be less favored than that of acetate group. EDDA forms two isomers, α-cis and β-cis. PDTA also forms two structural isomers due to the methyl group in the ligand.