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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 26, Number 2
JKCSEZ 26(2)
April 20, 1982

Title	Monooxo-bridged Binuclear Molybdenum (Ⅴ) Complexes (Ⅳ) 한 개 산소 가교 이핵몰리브덴 (Ⅴ) 착물 (제4보)
Author	Oh Sang Oh, Jong Dal Rhee 오상오, 이종달
Keywords
Abstract	한 개 산소 가교 이핵몰리브덴 (Ⅴ) 착물, Mo2O3(NCS)4(Bipy)2 (Bipy = bipyridine), Mo2O3(NCS)4(Phen)2 (Phen = 1,10-phenanthroline), 및 Mo2O3(NCS)4(Ox)2(OxH)2 (Ox = oxinato and OxH = oxine)이 합성되었다. 그들의 전자 및 적외선 스펙트라, 전기 전도도, 그리고 자화율을 측정하였다. 그 결과 이들 착물은 모두 전기적으로 중성이며 약 0.5BM 정도의 자기 모멘트를 가진 이량체였다. 그리고 oxine 착물, Mo2O3(NCS)2(Ox)2(OxH)2에서 oxine은 일부는 한 자리 리간드로, 일부는 두 자리 리간드로 결합하고 있는 듯 하다. The monooxo-bridged binuclear molybdenum(Ⅴ) complexes, Mo2O3(NCS)4(Bipy)2 (Bipy = bipyridine), Mo2O3(NCS)4(Phen)2 (Phen = 1,10-phenanthroline), and Mo2O3(NCS)4(Ox)2(OxH)2 (Ox = oxinato and OxH = oxine) have been prepared. Their electronic and IR spectra, electric conductivity, and magnetic susceptibility were measured. From the results all of th complexes turned out to be electroneutral dimers with about 0.5 BM, and in the oxine complex, Mo2O3(NCS)2(Ox)2(OxH)2, the oxine seems to bind partly as monodentate and partly as bidentate molecule.
Page	81 - 87
Full Text	PDF

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