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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 25, Number 3
JKCSEZ 25(3)
June 20, 1981

Title	Synthesis and Characterization of Substituted Pyridine Complexes of Molybdenum (Ⅰ). Substituted Pyridinium Salts of Oxopentaisothiocyanatomolybdates(Ⅴ) 몰리브덴의 피리딘계 착물합성과 그 성질 (제1보). 옥소이소티오시아나토몰리브덴 (Ⅴ) 의 치환 피리딘늄염
Author	Sang Oh Oh, Chang-Su Kim 오상오, 김창수
Keywords
Abstract	[MoO(NCS)5]2-의 벤조일피리딘늄 및 루티딘늄을 합성한 후 전기전도도, 자기모멘트, 가시 및 적외선스펙트라등에 이하여 이들의 구조를 조사하였다. 옥소오이소티오시아나토몰리브덴(Ⅴ)의 벤조일피리딘늄 및 루티딘늄염에서 티오시아나토의 질소가 몰리브덴과 결합되었으며 벤조일피리딘과 루티딘은 리간드가 아닌 양이온으로 존재함을 확인하였다. 이들 착물은 d-d전이와 전하이동전이가 일어 났으며 착물의 자기모멘트는 μspin-only 값과 거의 같았다. Benzoylpyridinium and lutidinium salts containing [MoO(NCS)5]2- have been synthesized. The complexes have been characterized by spectroscopic, magnetic susceptibility and conductivity studies. Benzoylpyridinium and lutidinium oxopentaisothiocyanatomolybdates(Ⅴ) arise from d-d and charge transfer transitions. The magnetic moments of the complexes are close to the spin-only values. The complex anions are mononuclear containing N-bonded NCS- ligand.
Page	177 - 182
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