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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 24, Number 5
JKCSEZ 24(5)
October 20, 1980 

 
Title
Reactions of Organostannyl Compounds with Unsaturated Compounds

유기주석화합물과 불포화화합물과의 반응
Author
Il-Kyu Lee, Bae-Seok Seo, Ghap-Ju Ghim

이일규, 서배석, 김갑주
Keywords
Abstract
Trimethylstannyl-diethylamine, -ethylsulfide, -methoxide 및 -hydroxide 등과 phenyl-isocyanate를 여러 온도에서 반응시킨 결과, 100℃ 이하에서는 triphenylisocyanurate만이 생성되었고, 150℃에서는 triphenylisocyanurate 와 diphenylcarbodiimide가 생성되었다. 한편, trimethylstannyldiethylamine과 chloral과의 반응에서는 N,N-diethylformamide와 trimethylstannyltrichloromethide가 생성되었으며, N-ethyl-N'-phenylcarbodiimide가 생성하였다.

Trimethylstannyl-diethylamine, trimethylstannylethylsulfide, trimethylstannylmethoxide and trimethylstannylhydroxide were reacted with phenylisocyanate at various temperatures. The product was only triphenylisocyanurate below 100℃ and the mixtures of triphenylisocyanurate and diphenylcarbodiimide were obtained at 150℃. Whereas, in the reaction of trimethylstannyldiethylamine with chloral, N,N-diethylformamide and trimethylstannyltrichloromethide were produced. The products from the reaction of N-ethylhexamethyldistannazane with phenylisothiocyanate were bis(trimethylstannyl) sulfide and N-ethyl-N'-phenylcarbodiimide.

Page
393 - 397
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