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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 23, Number 6
JKCSEZ 23(6)
December 20, 1979 

The Syntheses of Organostannyl Compounds by Grignard Reaction Catalyzed by Ether in Non-ethereal Media

비에테르성 용매중에서 에테르촉매를 사용한 그리냐르반응에 의한 유기스탄닐화합물의 합성
Bae Seok Sel, Il Kyu Lee

서배석, 이일규
몇가지 유기할로겐화물, 즉 브롬화에틸, 염화부틸, 브롬화페닐 및 염화벤질등을 탄화수소중에서 그리냐르법으로 무수사염화주석과 반응시켰다. 이때 소량의 에테르를 그리냐르반응단계에서 계내에 투입하엿을 때 보다 용이하게 반응이 진행되어 좋은 수율로 유기주석화합물들을 얻을 수 있었다.

Some alkyl or aryl halides, such as ethyl bromide, butyl chloride, phenyl bromide and benzyl chloride, were reacted by Grignard's method with anhydrous tin tetrachloride in hydrocarbon media. When small amounts of ether were added into the Grignard reaction step, the reaction proceeded rather smoothly and gave good yields of corresponding organotin compounds.

392 - 395
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