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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 22, Number 2
JKCSEZ 22(2)
April 20, 1978 

 
Title
Platinum(Ⅱ) Complexes of 2,2-bis(Methylaminomethyl)-1,3-dioxolane

2,2-비스(메틸아미노메틸)-1,3-dioxolane의 백금(Ⅱ) 착물
Author
Moo-Jin Jun

전무진
Keywords
Abstract
새로운 두자리 아민리간드 2,2-bis(메틸아미노메틸)-1,3-dioxolane(mexo)가 합성되었고 이 리간드로부터 디클로로 및 trans-R-cyclohexanediamine(R-chxn) 백금(Ⅱ) 착물이 합성되었다. 착물은 평면 사각형의 구조이며 원소분석, 핵자기공명, 흡수분광법 및 원편광이색성분광분석을 이용하여 리간드와 착물의 구조를 설명하였다.

The synthesis of a bidentate secondary amine ligand, 2,2-bis(methylaminomethyl-2,3-dioxolane(methylaminomethyl)-1,3-dioxolane(mexo) and the preparation of dichloro and trans-R-cyclohexanediamine platinum(Ⅱ) complexes of this ligand are reported. The structures of the ligand and complexes prepared have been elucidated via elemental analyses, nmr, electronic absorption, and CD spectra.

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99 - 104
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