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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 21, Number 5
JKCSEZ 21(5)
October 20, 1977 

 
Title
Application of the Projection Operator Technique to the Study of NMR Line Shape and Free Induction Decay Curve

NMR 흡수선 모양과 유도자기 자유감쇠곡선 연구에의 투영연산자법의 응용
Author
Jo W. Lee, Nak Jun Sung

이조웅, 성낙준
Keywords
Abstract
이 논문에서는 NMR 흡수선과 FID 곡선의 모양을 연구함에 있어서의 projection operation의 응용법을 탐색하였다. 이 projection operator법은 NMR 흡수선과 FID 함수를 연구하는데에 기초가 되는 한 벌의 hierarchy equation들을 유도하는데에 편리한 수단이 됨을 밝혔다. 축차근사법이나 적당한 decoupling 근사를 쓰면 이들 방정식은 NMR 흡수선이나 FID 함수를 이론적으로 계산하는데에 좋은 출발점이 될 수 있을 것이다. NMR 흡수선에 대한 간단한 linear response theory의 고찰과 흡수선과 FID 함수간의 관계도 기술하였다.

In this paper application of the projection operator technique to the study of NMR absorption line shape and free induction decay curve is explored. It is found that the projection operator technique can provide a convenient means for deriving a set of hierarchy equations which may serve as a good starting point for theoretical calculation of the absorption line and free induction decay function by successive approximation or by an appropriate decoupling approximation. A brief review of linear response theory of NMR line shape and the relation between the absorption line shape and free induction decay function are also described.

Page
362 - 371
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