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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 19, Number 5
JKCSEZ 19(5)
October 20, 1975 

Synthesis and Properties of the Quaternary Ammonium Salts Obtained from Phenylethyl Tosylate with Pyridine and N,N-Dimethyl p-Toluidine

Phenylethyl Tosylate 와 피라딘 및 N,N-디메틸 p-톨루이딘 과의 4급 암모늄염의 합성과 성질
Jae-hwan Choi, Soo-dong Yoh

최재환, 여수동
2-Phenylethyl tosylate를 피리딘 및 p-톨릴-N,N-디메틸아닐린과 반응시켜 대응하는 4급 암모늄염을 합성하여 NMR 및 IR로서 4급염을 확인하였고 그의 물리 및 화학정수를 비교하였다. 본실험에서 얻은 2-phentylethyl pyridinium tosylate는 benzyl pyridinium tosylate와 마찬가지 방법으로 아세톤 중에서도 합성이 가능하나 아세토니트릴중에서 수율이 훨씬 좋음을 알았다.

Some quaternary ammonium salts were synthesized from 2-phenylethyl tosylate with pyridine and N,N-dimethyl p-toluidine, which were identified by NMR and IR spectrometry and the comparison of their physico-chemical constant has been made. It is found that the yield of the salts synthesized were significantly improved in acetonitrile rather than in acetone.

351 - 354
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