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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 19, Number 2
JKCSEZ 19(2)
April 20, 1975 

Metal Complexes Containing Multidentate Ligands (Ⅰ). Cobalt (Ⅲ) Complexes of 1,10-Dibenzyltriethylenetetraamine and 1,10-Dibenzyl-5R-methyltriethylenetetraamine

1,10-디벤질트리에틸렌테트라아민과 1,10-디벤질-5R-메틸트리에틸렌테트라아민의 코발트(Ⅲ) 착물
Moo-Jin Jun, Chui Fan Liu

전무진, Chui Fan Liu
두개의 리간드 1,10-디벤질트리에틸렌테트라아민 (1,10-Be2trien)과 1,10-디벤질-5R-메틸트리에틸렌테트라아민(1,10-Be2-5R-Metrien)을 합성하고 이들 두 리간드의 디클로로 코발트(III) 착물을 제조하였다. 이 두 테트라아민 리간드는 코발트(III) 이온에 대하여 트란스 기하배위를 아주 잘 형성하였다.

The synthesis of two new ligands, 1,10-dibenzyltriethylenetetraamine (1,10-Be2trien) and 1,10-dibenzyl-5R-methyltriethylenetetraamine (1,10-Be2-5R-Metrien), and the preparation of the dichloro cobalt(Ⅲ) complexes of these ligands are reported. Both tetraamine ligands yield exclusively trans geometry upon coordination to the cobalt(Ⅲ) ion.

98 - 103
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