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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 19, Number 1
JKCSEZ 19(1)
February 20, 1975 

 
Title
3-Molybdo-9-tungstophosphoric Acid, 6-Molybdo-6-tungstophosphoric Acid and Their Reduction Products

3-몰리브도-9-텅스토인산, 6-몰리브도-6-텅스토인산 및 이들의 환원 생성물
Author
Kyoung Ran Im, Minjoong Yoon, Hyunsoo So

임경란, 윤민중, 소현수
Keywords
Abstract
3-몰리브도-9-텅스토인산, 6-몰리브도-6-텅스토인산과 이들의 1전자 및 전자 환원생성물을 합성하였다. 적외선 스펙트럼들로부터 이들이 모두 케긴 구조를 가짐을 확인하였다. 환원생성물의 폴라로그램과 전자흡수 스펙트럼들을 보고하였으며, 이들은 첨가된 각 전자가 한 몰리브덴원자에 국소화되어 있는 모형과 일치한다.

3-Molybdo-9-tungstophosphoric acid, 6-molybdo-6-tungstophosphoric acid and their one-electron and two-electron reduction products have been synthesized. Infrared spectra show that all of them have Keggin structure. Polarograms and optical spectra of the reduced species are reported. Both data indicate that each additional electron is localized on a molybdenum atom.

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16 - 20
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