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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 18, Number 6
JKCSEZ 18(6)
December 20, 1974 

The Application of the Pseudo Molecular Complex to Thermal Polymerization (Ⅰ). Proposal of A New Initiation Mechanism

의사분자 착물의 응용 (제1보). 열중합 개시기구 제안
Byung Kack Park

다수의 열공중합 반응조들에 대하여 pseudo molecular complex 형성이 가능한가를 이론적으로 조사하였던바 예외없이 pseudo molecular complex 형성이 가능하였다. 즉, pseudo molecular complex 형성이 공중합반응조들의 공통성임을 발견하였다. 그래서 열공중합반응은 pseudo molecular complex를 경유하여 반응이 진행하는 하나의 가능한 개시기구를 제안하였다.

A mechanistic possibility for the initiation of the thermal polymerization reactions are envisaged theoretically. As result of the considerations, it is assumed that the thermal polymerization reactions take place via the pseudo molecular complex which has been supposed to be an intermediate in the transition state of Diels-Alder reactions.

447 - 452
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