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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 18, Number 1
JKCSEZ 18(1)
February 20, 1974 

 
Title
Extended Huckel Calculations of the Effect of Sulfenyl, Sulfinyl and Sulfonyl Groups on the Reactivity of Halides in SN2 Reactions

할라이드의 SN2 형 반응성에 미치는 술페닐, 술피닐 및 술포닐기의 효과에 대한 확장 Huckel 계산
Author
Ui Rak Kim, Kyu Yong Lee, Sun Ho Bai, Ikchoon Lee

김의락, 이규용, 배선호, 이익춘
Keywords
Abstract
확장 Huckel법을 사용하여 술페닐, 술피닐 및 술포닐기가 할라이드의 SN2형 반응에 미치는 효과를 고찰하고 각종 반응성 지수를 비교, 검토한 결과 bond formation과정의 반응성 지수중 Frontier electron에 의한 것이 가장 합리적인 것임을 밝혔다.

Extended Huckel calculations have been carried out to study the effect of sulfenyl, sulfinyl and sulfonyl groups on the reactivity of halides in SN2 reactions. Results indicate that the most reasonable reactivity index is that based on the Frontier electron for the bond formation process.

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