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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 17, Number 6
JKCSEZ 17(6)
December 20, 1973 

Afterpolymerization and Depolymerization of Poly-ε-caproamide in Solid State

고체상태에서 Poly-ε-caproamide의 후중합 및 해중합에 관한 연구
Jung-Ji Moon, Dong-ho Lee, Tae-Oan Ahn

문정지, 이동호, 안태완
고체상태에서 poly-ε-caproamide의 후중합과 해중합을 질소흐름 및 밀봉의 두 조건하에서 행하였다. 중합도는 반응시간과 온도에 따라 증가하여 결국 평형에 도달하며, 산소의 존재하에서는 산화에 의해 해중합되어 중합도가 감소하게 된다. 중합도가 서로 다른 poly-ε-caproamide를 반응시키면 평행에 도달했을 때의 중합도는 동일하게 된다.

The afterpolymerization and depolymerization of poly-ε-caproamide in solid state have been studied under two different reaction conditions, nitrogen flow and sealed state. The degree of polymerization (P) of nylon 6 increased with the increase in reaction time and temperature, and then reacted finally an equilibrium. In the presence of oxygen, P decreased by increasing the reaction time due to the oxidation reaction. Under certain reaction condition, the change of P for different initial degree of polymerization (P0) tendered toward unity in equilibrium.

450 - 454
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