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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 17, Number 4
JKCSEZ 17(4)
August 20, 1973 

The Preparation of Perfluorinated Organometallic Compounds via Vinyllithium Compounds of Alicyclic 1,2-Dihalopolyfluoroolefins

Alicyclic 1,2-디할로폴리플루오르올레핀으로 부터 비닐리튬 화합물과 Perfluorinated 유기금속화합물의 합성
Joseph D. Park, Sam Kwon Choi

박달조, 최삼권
폴리플루오로알켄닐리튬 화합물들이 1,2-dihalopolyfluorocycloalkenes와 알킬리튬시약과의 교환반응에 의하여 합성되었다. 수은, 비소와 디메틸게르마늄할로겐화물과의 여러 가지 반응이 저술되어 있고 또 이 화합물들의 화학적성질에 대하여 고찰하였다.

Polyfluorocycloalkenyllithium compounds have been prepared by exchange reaction with 1,2-dihalopolyfluorocycloalkenes and alkyllithium reagents. Their reactions with mercuric, arsenic and dimethyl germanium halides are described and the chemistry of these compounds discussed.

286 - 297
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