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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 17, Number 3
JKCSEZ 17(3)
June 20, 1973 

Nucleophilic Displacement at Sulfur Center (Ⅱ). Solvolysis of Benzenesulfonyl Chloride in Acetone-Water Mixtures

유황의 친핵치환반응 (제2보). 아세톤-물 혼합용매에서의 염화벤젠슬포닐의 가용매반응
Wang Ki Kim, Ikchoon Lee

김왕기, 이익춘
10∼50wt. %아세톤-물 혼합 용매 속에서의 benzenesulfonyl chloride 치환체들의 가용매반응을 속도론적으로 연구한 결과 SN2 성격이 지배적이었으며 general base-catalyzed반응이 일어나고 있음을 알았다.

Kinetic studies of p-substituted benzenesulfonyl chlorides have been carried out in 10~50 wt. % water-acetone mixtures. Results show that SN2 character almost predominates and general base-catalyzed reaction occurs.

163 - 168
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