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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 16, Number 1
JKCSEZ 16(1)
February 20, 1972 

 
Title
Theoretical Studies on the Polymerization of Divinylbenzene

Divinylbenzene 중합의 이론적 고찰
Author
Tae-oan Ahn, Dong-ho Lee

안태완, 이동호
Keywords
Abstract
Divinylbenzene의 중합에 있어서 gel point에서의 점도가 일정하다는 가정을 사용하여 점도 방정식, 점도와 분자량과의 관계식 및 사슬이동 방정식 등의 상호 관계를 연구하였다. 중합도 대신에 Gel time을 측정하여 사슬이동상수 Cv을 계산해 낼 수 있는 새로운 식을 제안하였다.

Using an assumption of isoviscosity at the gel-point in the polymerization of divinylbenzene, the relations between viscosity equation, viscosity-molecular weight, and the chain transfer equation have been studied. A new equation for the calculation of chain transfer constant, Ctr, by measuring the gel time in place of the degree of polymerization has been suggested.

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46 - 49
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