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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 15, Number 5
JKCSEZ 15(5)
October 20, 1971 

Kinetics of the Solvolysis of Benzyl Bromides in Alcohols

브롬화벤젠의 알코올에 의한 용매분해에 관한 반응속도론적 연구
Yong-Jin Lim, Soo-Dong Yoh, Soon-Yung Hong

임용진, 여수동, 홍순영
The kinetics of the solvolysis of benzyl and p-or m-substituted benzyl bromides in various alcohols have been determined by an electric conductivity method. From these reactions, a curved Hammett plot is obtained and a mechanism is proposed to account for the nonlinear behavior observed. In addition, effects of solvent polarity on the activation parameters for the solvolysis of benzyl bromides are discussed.
219 - 222
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