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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 15, Number 4
JKCSEZ 15(4)
August 20, 1971 

Solvolysis of p-Chlorobenzyl Chloride in Various Aqueous Mixtures

여러가지 물혼합용매 속에서 p-Chlorobenzyl Chloride의 가용매분해
Suk-Kee Lee, Euk-Suk Lee

이석기, 이억석
The thermodynamic parameters for the solvolysis of the p-chlorobenzyl chloride taking place in the various aqueous mixtures were determined. From the application of these data to the formula δMΔH≠ = a'Y + bδMΔS≠ the following conclusion was obtained: That the substrate constant a' differs in different aqueous solvent was found, and using each a' value the solvolysis mechanism of p-chlorobenzyl chloride in each aqueous mixture can be determined.
205 - 209
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